CAS 14635-75-7|Nitrosonium tetrafluoroborate 98%|nitrosonium tetrafluoroborate|Nitrosyl tetrafluoroborate|iminooxidanium; tetrafluoroboranuide|Nitrosyl tetrafluoroborate|Nitrosonium tetrafluoroborat...

基本信息

化学结构

分子式

BF₄NO

分子量

116.8107128

精确质量

117.00090691

电荷

InChI

InChI=1S/BF4.NO/c2-1(3,4)5;1-2/q-1;+1

InChIKey

KGCNVGDHOSFKFT-UHFFFAOYSA-N

Canonic Smiles

F[B-](F)(F)F.[O+]#N

Isomeric Smiles

N#[O+].[B-](F)(F)(F)F

计算属性

JChem

质子受体

质子供体

LogD (pH = 5.5)

-1.13

LogD (pH = 7.4)

-1.13

Log P

-1.13

摩尔折射率

6.0052

极化性

3.1085358

极化表面积

0.0

可自由旋转的化学键

里宾斯基五规则

true

数据来源

名称和标识

IUPAC传统名

nitrosonium tetrafluoroborate

别名

Nitrosonium tetrafluoroborate 98%Nitrosyl tetrafluoroborateNitrosyl tetrafluoroborateNitrosonium tetrafluoroborate四氟硼酸亚硝鎓亚硝四氟硼酸盐四氟硼酸亚硝Nitrosonium tetrafluoroborate

IUPAC标准名

iminooxidanium; tetrafluoroboranuide

名称和标识

数据登录号

MDL号

MFCD00011433

CAS号

14635-75-7

PubChem SID

2485036024886632162084753

EC号

238-679-2

PubChem CID

11137142

默克索引号

146649

数据登录号

化合物性质

理化性质

密度

2.185

熔点

250(subl.)°C

250°C subl.

沸点

250°C/0.01mm subl.

化合物性质

分子相关蛋白质

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分子图谱

暂无数据

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描述信息

Sigma Aldrich

175064

包装
5, 25, 50 g in amber poly

Apollo Scientific

PC5290

Versatile crystalline nitrosating agent. Converts arylamines to aryl fluorides via diazonium tetrafluoroborates: Chem. Ber., 88, 1939 (1995).. in Teflon bottles

描述信息

参考文献

PubChem文献

数据源提供

• With excess reagent, oxidation of the isoxazoline to the isoxazole occurs.

• Crystalline nitrosating agent: Secondary amines to nitrosamines: Chem. Ber., 89, 2374 (1956); deamination of primary amides: J. Org. Chem., 30, 2386 (1965); conversion of arylhydrazines to azides: Tetrahedron Lett., 28, 5091 (1987). In organic solvents, converts arylamines directly to diazonium tetrafluoroborates which undergo the Balz-Schiemann reaction (see Tetrafluoroboric acid, L14037) in situ to give high yields of aryl fluorides: Chem. Ber., 88, 1939 (1955); EP 430,434 (1991). Methyl or methoxy substituted aromatics in acetonitrile give the nitrosoaromatics in good yield: J. Org. Chem., 59, 5573 (1994).

• Undergoes an interesting insertion reaction with diarylcyclopropanes: Chem. Lett., 233 (1988):

• Convenient catalyst for iodination of aromatics by iodide ion with air as oxidant: J. Org. Chem., 53, 3548 (1988), or for addition of iodine (or iodine + nucleophile) to alkenes: Acta Chem. Scand. B, 43, 902 (1989).

参考文献

生物活性

PubChem BioAssay

生物活性

名称和标识

IUPAC传统名

nitrosonium tetrafluoroborate

别名

IUPAC标准名

iminooxidanium; tetrafluoroboranuide

数据登录号

MDL号

MFCD00011433

CAS号

14635-75-7

PubChem SID

2485036024886632162084753

EC号

PubChem CID

默克索引号

描述信息

175064

包装
5, 25, 50 g in amber poly

Apollo Scientific

PC5290

Versatile crystalline nitrosating agent. Converts arylamines to aryl fluorides via diazonium tetrafluoroborates: Chem. Ber., 88, 1939 (1995).. in Teflon bottles

参考文献

PubChem文献

数据源提供

• With excess reagent, oxidation of the isoxazoline to the isoxazole occurs.

• Undergoes an interesting insertion reaction with diarylcyclopropanes: Chem. Lett., 233 (1988):

生物活性

PubChem BioAssay

化合物性质

理化性质

密度

2.185

熔点

250(subl.)°C

250°C subl.

沸点

250°C/0.01mm subl.

化合物信息

ID:98307