CAS 5381-99-7|Salicyl chlorophosphite|2-Chloro-4H-1,3,2-benzodioxaphosphorin-4-one|2-chloro-2,4-dihydro-1,3,2-benzodioxaphosphinin-4-one|2-chloro-1,3,2-benzodioxaphosphinin-4-one|Salicyl Phosphoroch...

基本信息

化学结构

分子式

C₇H₄ClO₃P

分子量

202.531621

精确质量

201.9586583

电荷

InChI

InChI=1S/C7H4ClO3P/c8-12-10-6-4-2-1-3-5(6)7(9)11-12/h1-4H

InChIKey

BVOITXUNGDUXRW-UHFFFAOYSA-N

Canonic Smiles

ClP1OC(=O)c2c(O1)cccc2

Isomeric Smiles

O1C(=O)c2c(cccc2)OP1Cl

计算属性

JChem

质子受体

质子供体

LogD (pH = 5.5)

2.4658

LogD (pH = 7.4)

2.4658

Log P

2.4658

摩尔折射率

46.1254

极化性

17.577293

极化表面积

35.53

可自由旋转的化学键

里宾斯基五规则

true

数据来源

名称和标识

别名

Salicyl chlorophosphite2-Chloro-4H-1,3,2-benzodioxaphosphorin-4-oneSalicyl PhosphorochloriditeNSC 402092-Chloro-4H-1,2,3-benzodioxaphosphorin-4-one 90%SalPCl2-Chloro-1,3,2-benzodioxaphosphorin-4-one2-氯-1,3,2-苯并二氧磷杂环己烷-4-酮2-Chloro-4H-benzo[d][1,3,2]dioxaphosphinin-4-one2-Chloro-4H-1,3,2-benzodioxaphosphorin-4-one2-氯-4H-1,3,2-苯并二氧磷-4-酮

IUPAC标准名

2-chloro-2,4-dihydro-1,3,2-benzodioxaphosphinin-4-one

IUPAC传统名

2-chloro-1,3,2-benzodioxaphosphinin-4-one

名称和标识

数据登录号

CAS号

5381-99-7

Beilstein号

1311951

MDL号

MFCD00013353

PubChem SID

2485942524854081162074928

PubChem CID

237010

数据登录号

化合物性质

分子相关蛋白质

暂无数据

点击上传数据

分子图谱

暂无数据

点击上传数据

描述信息

Apollo Scientific

OR3651T

Highly reactive cyclic phosphitylating reagent which provides fast coupling rates, & hydrolic cleavage that occurs more readily than with acrylic analogs.

Sigma Aldrich

324124

Application
Reagent used in phosphorylation and phosphitylation of alcohols and in the formation of H-phosphonates.
包装
5, 25 g in glass bottle

23514

Other Notes
用于核苷和碳水化合物的亚磷酸化剂1,2,3；由醇合成三磷酸酯和 1-硫代三磷酸酯4

TRC

C365000

Highly reactive cyclic phosphitylating reagent which provides fast coupling rates, and hydrolytic cleavage occurs more readily than with acyclic analogs.

描述信息

参考文献

PubChem文献

数据源提供

• Bannwarth,W. & Kung, E.: Tetrahedron Lett., 30, 4219 (1989)

参考文献

生物活性

PubChem BioAssay

生物活性

名称和标识

别名

IUPAC标准名

2-chloro-2,4-dihydro-1,3,2-benzodioxaphosphinin-4-one

IUPAC传统名

2-chloro-1,3,2-benzodioxaphosphinin-4-one

数据登录号

CAS号

5381-99-7

Beilstein号

1311951

MDL号

MFCD00013353

PubChem SID

2485942524854081162074928

PubChem CID

237010

描述信息

Apollo Scientific

OR3651T

Highly reactive cyclic phosphitylating reagent which provides fast coupling rates, & hydrolic cleavage that occurs more readily than with acrylic analogs.

Sigma Aldrich

324124

Application
Reagent used in phosphorylation and phosphitylation of alcohols and in the formation of H-phosphonates.
包装
5, 25 g in glass bottle

23514

Other Notes
用于核苷和碳水化合物的亚磷酸化剂1,2,3；由醇合成三磷酸酯和 1-硫代三磷酸酯4

TRC

C365000

Highly reactive cyclic phosphitylating reagent which provides fast coupling rates, and hydrolytic cleavage occurs more readily than with acyclic analogs.

参考文献

PubChem文献

数据源提供

• Bannwarth,W. & Kung, E.: Tetrahedron Lett., 30, 4219 (1989)

生物活性

PubChem BioAssay

化合物性质

化合物信息

ID:87888