CAS 593-56-6|O-methylhydroxylamine hydrochloride|O-Methylhydroxylamine hydrochloride|O-methylhydroxylamine hydrochloride|O-Methylhydroxylamine hydrochloride 98%|Methoxylamine hydrochloride|Methoxyam...

基本信息

化学结构

分子式

CH₆ClNO

分子量

83.51744

精确质量

83.0137915

电荷

InChI

InChI=1S/CH5NO.ClH/c1-3-2;/h2H2,1H3;1H

InChIKey

XNXVOSBNFZWHBV-UHFFFAOYSA-N

Canonic Smiles

CON.Cl

Isomeric Smiles

NOC.Cl

计算属性

JChem

质子受体

质子供体

LogD (pH = 5.5)

-0.39036477

LogD (pH = 7.4)

-0.36289734

Log P

-0.36253566

摩尔折射率

12.331

极化性

4.8056803

极化表面积

35.25

可自由旋转的化学键

里宾斯基五规则

true

数据来源

名称和标识

别名

O-Methylhydroxylamine hydrochlorideMethoxylamine hydrochlorideO-Methylhydroxylamine hydrochloride 98%Methoxyamine hydrochlorideO-METHYLHYDROXYLAMINE HYDROCHLORIDEMETHOXYAMINE HYDROCHLORIDEMethoxylammonium Chloride甲氧基胺盐酸盐O-甲胲盐酸盐甲氧胺盐酸盐METHOXYAMINE(Aminooxy)methane HydrochlorideMethoxyammonium ChlorideMethoxylamine hydrochloride solutionMethoxylamine HydrochlorideO-Methoxyamine HydrochlorideHydroxylamine Methyl Ether HydrochlorideN-Methoxylamine Hydrochloride甲氧基胺盐酸盐溶液甲氧胺盐酸盐Methoxylamine hydrochloride

IUPAC传统名

O-methylhydroxylamine hydrochloride

IUPAC标准名

O-methylhydroxylamine hydrochloride

名称和标识

数据登录号

CAS号

593-56-6

PubChem SID

248535982485350216203527124885282

Beilstein号

EC号

MDL号

PubChem CID

默克索引号

数据登录号

化合物性质

分子相关蛋白质

暂无数据

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分子图谱

暂无数据

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描述信息

MP Biomedicals

02155405

Hydrochloride

05208450

MP Biomedicals Rare Chemical collection

Sigma Aldrich

226904

Application
用于制备 O-甲基肟的试剂1,2用于由醛3 或酮制备 O-甲基肟。4
包装
1, 5 g in glass bottle
25 g in poly bottle
100 g in glass bottle

225517

包装
25, 100 g in glass bottle

67546

Other Notes
用于保护 1,4-二烯-3-酮体系中酮基团的试剂1；用于衍生供气液色谱法检测的类固醇酮基团的试剂2；用于通过气相色谱法快速测定糖蛋白中中性糖和氨基糖的试剂3；用于酮的立体选择性还原的试剂4

TRC

M262720

Methoxylamine is a methoxime derivative used as internal standard for Prostaglandin assays by gas chromatography-mass spectrometry.

描述信息

参考文献

PubChem文献

数据源提供

• Herold, D.A. et al.: Prostaglandins, 33, 599 (1987)

• In the presence of KO-t-Bu and a copper catalyst in DMF, aminates nitroarenes at the ortho (predominantly) and para positions: J. Org. Chem., 61, 442 (1996).

• Reacts with aldehydes and ketones to give O-methyloximes: J. Org. Chem., 27, 914 (1962); 28, 1523 (1963); Anal. Biochem., 22, 284 (1968). Open-chain aldoses have been prepared by ozonolysis of the methoximes of fully-acylated sugars: J. Org. Chem., 54, 4957 (1989).

• As with oximes, the lithiation of methoximes results in abstraction of a proton syn to the oxygen function (coordination stabilization): J. Org. Chem., 41, 439 (1976). For a review of the alkylation of carbonyl compounds via their nitrogen-containing derivatives, see: Synthesis, 517 (1983).

参考文献

生物活性

PubChem BioAssay

生物活性

名称和标识

别名

IUPAC传统名

O-methylhydroxylamine hydrochloride

IUPAC标准名

O-methylhydroxylamine hydrochloride

数据登录号

CAS号

593-56-6

PubChem SID

248535982485350216203527124885282

Beilstein号

EC号

MDL号

PubChem CID

默克索引号

描述信息

Hydrochloride

MP Biomedicals Rare Chemical collection

Sigma Aldrich

226904

Application
用于制备 O-甲基肟的试剂1,2用于由醛3 或酮制备 O-甲基肟。4
包装
1, 5 g in glass bottle
25 g in poly bottle
100 g in glass bottle

225517

包装
25, 100 g in glass bottle

67546

TRC

M262720

Methoxylamine is a methoxime derivative used as internal standard for Prostaglandin assays by gas chromatography-mass spectrometry.

参考文献

PubChem文献

数据源提供

• Herold, D.A. et al.: Prostaglandins, 33, 599 (1987)

• In the presence of KO-t-Bu and a copper catalyst in DMF, aminates nitroarenes at the ortho (predominantly) and para positions: J. Org. Chem., 61, 442 (1996).

生物活性

PubChem BioAssay

化合物性质

化合物信息

ID:69545