包装 100, 500 g in glass bottle Application Reactant for: • Direct amidation of azoles with formamides via metal-free C-H activation in the presence of tert-butyl perbenzoate1 • Vilsmeier-type reactions of pyrazoles with amides in the presence of phosphorous oxychloride2 • CO-free aminocarbonylation of N-substituted formamides with aryl iodides/bromides catalyzed by palladium acetate and Xantphos for synthesis of arylamides3 • Synthesis of alternating copolymers for organic photovoltaic applications4 • One-pot double functionalization of π-deficient heterocyclic lithium reagents5 • Synthesis of thermally stable piezofluorochromic aggregation-induced emission compounds6
Other Notes 用于甲酰基转移至格氏试剂的反应7 Application Reactant for: • Direct amidation of azoles with formamides via metal-free C-H activation in the presence of tert-butyl perbenzoate1 • Vilsmeier-type reactions of pyrazoles with amides in the presence of phosphorous oxychloride2 • CO-free aminocarbonylation of N-substituted formamides with aryl iodides/bromides catalyzed by palladium acetate and Xantphos for synthesis of arylamides3 • Synthesis of alternating copolymers for organic photovoltaic applications4 • One-pot double functionalization of π-deficient heterocyclic lithium reagents5 • Synthesis of thermally stable piezofluorochromic aggregation-induced emission compounds6
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• Reaction with Grignard or alkyllithium reagents gives aldehydes in high yield: Angew. Chem. Int. Ed., 20, 878 (1981); Org. Synth. Coll., 7, 451 (1990).
有害性 (Xn)