CAS 7783-99-5|silver(1+) ion nitrite|亚硝酸银|Silver nitrite|silver(1+) ion nitrite

基本信息

化学结构

分子式

AgNO₂

分子量

153.8737

精确质量

152.89800025

电荷

InChI

InChI=1S/Ag.HNO2/c;2-1-3/h;(H,2,3)/q+1;/p-1

InChIKey

KKKDGYXNGYJJRX-UHFFFAOYSA-M

Canonic Smiles

[O-]N=O.[Ag+]

Isomeric Smiles

N(=O)[O-].[Ag+]

计算属性

JChem

Acid pKa

3.3200002

质子受体

质子供体

LogD (pH = 5.5)

0.16613764

LogD (pH = 7.4)

0.16613764

Log P

0.16613764

摩尔折射率

7.6

极化性

2.4691868

极化表面积

52.49

可自由旋转的化学键

里宾斯基五规则

true

数据来源

产品目录

学术数据

数据来源

名称和标识

IUPAC标准名

silver(1+) ion nitrite

别名

亚硝酸银Silver nitrite

IUPAC传统名

silver(1+) ion nitrite

名称和标识

数据登录号

CAS号

7783-99-5

EC号

232-041-7

MDL号

MFCD00003413

PubChem SID

248883212487880224853618162226378

PubChem CID

160904

默克索引号

148519

数据登录号

化合物性质

分子相关蛋白质

暂无数据

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分子图谱

暂无数据

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描述信息

Sigma Aldrich

227188

包装
10, 50 g in glass bottle

545015

包装
5, 25 g in glass bottle

描述信息

参考文献

PubChem文献

数据源提供

• Forms complexes with alkenes, used in the separation of mixtures; see, e.g.: Org. Synth. Coll., 5, 315 (1973).

• For a brief feature on uses of the reagent in synthesis, see: Synlett, 3016 (2005).

• Promotes the reactivity of NCS in the cleavage of 2-acylated 1,3-dithianes: Synthesis, 17 (1969), and of NBS in the 1-bromination of terminal alkynes: Angew. Chem. Int. Ed., 23, 727 (1984).

• The Hunsdiecker reaction of Ag salts of carboxylic acids with Br₂ provides alkyl bromides with one less carbon atom which is lost as CO₂; see, e.g.: Org. Synth. Coll., 3, 578 (1955). Reviews: Chem. Rev., 56, 219 (1956); Org. React., 9, 332 (1957). Compare also Mercury(II) oxide, A16157.

• In combination with Br₂ or I₂ in refluxing methanol, brings about the rearrangement of acetophenones to methyl arylacetates, a reaction previously induced by thallium(III) nitrate: J. Chem. Soc., Perkin 1, 235 (1982):

• For the alkylation of substrates by radicals derived from decarboxylation of acids, see Trimethylacetic acid, A10776.

参考文献

生物活性

PubChem BioAssay

生物活性

数据来源

产品目录

学术数据

名称和标识

IUPAC标准名

silver(1+) ion nitrite

别名

亚硝酸银Silver nitrite

IUPAC传统名

silver(1+) ion nitrite

数据登录号

CAS号

7783-99-5

EC号

232-041-7

MDL号

MFCD00003413

PubChem SID

248883212487880224853618162226378

PubChem CID

160904

默克索引号

148519

描述信息

Sigma Aldrich

227188

包装
10, 50 g in glass bottle

545015

包装
5, 25 g in glass bottle

参考文献

PubChem文献

数据源提供

• Forms complexes with alkenes, used in the separation of mixtures; see, e.g.: Org. Synth. Coll., 5, 315 (1973).

• For a brief feature on uses of the reagent in synthesis, see: Synlett, 3016 (2005).

• Promotes the reactivity of NCS in the cleavage of 2-acylated 1,3-dithianes: Synthesis, 17 (1969), and of NBS in the 1-bromination of terminal alkynes: Angew. Chem. Int. Ed., 23, 727 (1984).

• For the alkylation of substrates by radicals derived from decarboxylation of acids, see Trimethylacetic acid, A10776.

生物活性

PubChem BioAssay

化合物性质

化合物信息

ID:132101