物质信息
ID:739816
名称和标识
IUPAC标准名
silver(1+) ion nitrite
别名
Silver nitrite亚硝酸银
IUPAC传统名
silver(1+) ion nitrite
化合物性质
安全信息
欧盟危险性物质标志
刺激性 (Xi)
环境危害性 (N)
氧化性 (O)危险公开号
8-36/38-50/53
安全公开号
17-26-37-60-61
GHS危险品标识
氧化性气体，1类
氧化性液体，类别1,2,3
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
对水环境的危害
急性危害，类别1
慢性危害，类别1,2
GHS危险声明
H272-H400-H410-H315-H319
联合国危险货物编号
UN2627
联合国危险货物包装类别(PG)
II
保存注意事项
Light Sensitive
联合国危险货物等级
5.1
GHS警示性声明
P221-P280G-P273-P305+P351+P338-P501A
TSCA收录
是
产品相关信息
纯度
99% (metals basis)
理化性质
外观
Crystalline
熔点
140°C dec.
密度
4.45
描述信息
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分子图谱
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参考文献
• Forms complexes with alkenes, used in the separation of mixtures; see, e.g.: Org. Synth. Coll., 5, 315 (1973).
• For a brief feature on uses of the reagent in synthesis, see: Synlett, 3016 (2005).
• Promotes the reactivity of NCS in the cleavage of 2-acylated 1,3-dithianes: Synthesis, 17 (1969), and of NBS in the 1-bromination of terminal alkynes: Angew. Chem. Int. Ed., 23, 727 (1984).
• The Hunsdiecker reaction of Ag salts of carboxylic acids with Br2 provides alkyl bromides with one less carbon atom which is lost as CO2; see, e.g.: Org. Synth. Coll., 3, 578 (1955). Reviews: Chem. Rev., 56, 219 (1956); Org. React., 9, 332 (1957). Compare also Mercury(II) oxide, A16157.
• In combination with Br2 or I2 in refluxing methanol, brings about the rearrangement of acetophenones to methyl arylacetates, a reaction previously induced by thallium(III) nitrate: J. Chem. Soc., Perkin 1, 235 (1982):
• For the alkylation of substrates by radicals derived from decarboxylation of acids, see Trimethylacetic acid, A10776.