Packaging 100, 500 g in glass bottle Application Reactant for: • Direct amidation of azoles with formamides via metal-free C-H activation in the presence of tert-butyl perbenzoate1 • Vilsmeier-type reactions of pyrazoles with amides in the presence of phosphorous oxychloride2 • CO-free aminocarbonylation of N-substituted formamides with aryl iodides/bromides catalyzed by palladium acetate and Xantphos for synthesis of arylamides3 • Synthesis of alternating copolymers for organic photovoltaic applications4 • One-pot double functionalization of π-deficient heterocyclic lithium reagents5 • Synthesis of thermally stable piezofluorochromic aggregation-induced emission compounds6
Other Notes Used in formyl transfer to Grignard reagents7 Application Reactant for: • Direct amidation of azoles with formamides via metal-free C-H activation in the presence of tert-butyl perbenzoate1 • Vilsmeier-type reactions of pyrazoles with amides in the presence of phosphorous oxychloride2 • CO-free aminocarbonylation of N-substituted formamides with aryl iodides/bromides catalyzed by palladium acetate and Xantphos for synthesis of arylamides3 • Synthesis of alternating copolymers for organic photovoltaic applications4 • One-pot double functionalization of π-deficient heterocyclic lithium reagents5 • Synthesis of thermally stable piezofluorochromic aggregation-induced emission compounds6
References
PubChem Literature
From Data Sources
• Reaction with Grignard or alkyllithium reagents gives aldehydes in high yield: Angew. Chem. Int. Ed., 20, 878 (1981); Org. Synth. Coll., 7, 451 (1990).
Harmful (Xn)