CAS 116-17-6|TRIISOPROPYL PHOSPHITE|Triisopropyl phosphite|亚磷酸三异丙酯|tris(propan-2-yl) phosphite|triisopropyl phosphite|Triisopropyl phosphite tech. 90%|Phosphorous acid triisopropyl ester

基本信息

化学结构

分子式

C₉H₂₁O₃P

分子量

208.235001

精确质量

208.12283116

电荷

InChI

InChI=1S/C9H21O3P/c1-7(2)10-13(11-8(3)4)12-9(5)6/h7-9H,1-6H3

InChIKey

SJHCUXCOGGKFAI-UHFFFAOYSA-N

Canonic Smiles

CC(OP(OC(C)C)OC(C)C)C

Isomeric Smiles

P(OC(C)C)(OC(C)C)OC(C)C

计算属性

JChem

质子受体

质子供体

LogD (pH = 5.5)

3.1726868

LogD (pH = 7.4)

3.1727

Log P

3.1727

摩尔折射率

55.4789

极化性

22.123232

极化表面积

27.69

可自由旋转的化学键

里宾斯基五规则

true

数据来源

名称和标识

别名

TRIISOPROPYL PHOSPHITE亚磷酸三异丙酯Triisopropyl phosphiteTriisopropyl phosphite tech. 90%Phosphorous acid triisopropyl ester

IUPAC标准名

tris(propan-2-yl) phosphite

IUPAC传统名

triisopropyl phosphite

名称和标识

数据登录号

CAS号

EC号

MDL号

Beilstein号

PubChem SID

PubChem CID

数据登录号

化合物性质

分子相关蛋白质

暂无数据

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分子图谱

暂无数据

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描述信息

MP Biomedicals

05219422

MP Biomedicals Rare Chemical collection

Sigma Aldrich

T67806

包装
100, 500 mL in glass bottle

描述信息

参考文献

PubChem文献

数据源提供

• Convenient means of introduction of an isopropyl group into an aromatic ring by Friedel-Crafts alkylation. Using nitromethane as solvent, rearrangement of existing groups can be avoided: Synthesis, 423 (1972).

• The complex with CuCl, the "Moser" catalyst, promotes the cyclopropanation of alkenes by diazoalkanes: J. Am. Chem. Soc., 91, 1135 (1969). For comparison with other catalysts, see: Synthesis, 787 (1981).

• Reagent for the preparation of phosphonate esters by the Arbuzov reaction; cf Triethyl phosphite, L00339. Has the advantage over primary phosphites that the bulky alkyl groups minimize the product of self-alkylation. For an example (diisopropyl methanephosphonate), see: Org. Synth. Coll., 4, 325 (1963).

• The combination with Pd(OAc)₂ is reported to be an efficient catalyst system for cross-coupling of arylboronic acids with both aryl bromides and chlorides: Chem. Eur. J., 6, 1830 (2000).

参考文献

生物活性

PubChem BioAssay

生物活性

名称和标识

别名

TRIISOPROPYL PHOSPHITE亚磷酸三异丙酯Triisopropyl phosphiteTriisopropyl phosphite tech. 90%Phosphorous acid triisopropyl ester

IUPAC标准名

tris(propan-2-yl) phosphite

IUPAC传统名

triisopropyl phosphite

数据登录号

CAS号

EC号

MDL号

Beilstein号

PubChem SID

PubChem CID

描述信息

MP Biomedicals Rare Chemical collection

Sigma Aldrich

T67806

包装
100, 500 mL in glass bottle

参考文献

PubChem文献

数据源提供

• The combination with Pd(OAc)₂ is reported to be an efficient catalyst system for cross-coupling of arylboronic acids with both aryl bromides and chlorides: Chem. Eur. J., 6, 1830 (2000).

生物活性

PubChem BioAssay

化合物性质

化合物信息

ID:89799