CAS 114615-82-6|tetrapropylammonium rutheniumoylolate|tetrapropylazanium rutheniumoylolate|Tetrapropylammonium perruthenate|四丙基高钌酸铵|Tetrapropylammonium perruthenate|TPAP|四正丙基过钌(VII)酸铵...

基本信息

化学结构

分子式

C₁₂H₂₈NO₄Ru

分子量

351.42502

精确质量

352.10618238

电荷

InChI

InChI=1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;

InChIKey

NQSIKKSFBQCBSI-UHFFFAOYSA-N

Canonic Smiles

[O-][Ru](=O)(=O)=O.CCC[N+](CCC)(CCC)CCC

Isomeric Smiles

CCC[N+](CCC)(CCC)CCC.O=[Ru](=O)(=O)[O-]

计算属性

JChem

LogD (pH = 7.4)

-0.45

LogD (pH = 5.5)

-0.45

Log P

-0.45

可自由旋转的化学键

质子供体

质子受体

里宾斯基五规则

true

极化表面积

0.00

极化性

25.47

摩尔折射率

72.99

数据来源

名称和标识

IUPAC传统名

tetrapropylammonium rutheniumoylolate TPAP

IUPAC标准名

tetrapropylazanium rutheniumoylolate

别名

Tetrapropylammonium perruthenate四丙基高钌酸铵Tetrapropylammonium perruthenateTPAP四正丙基过钌(VII)酸铵Tetra-n-propylammonium perruthenate(VII)TPAPTetrapropylammonium perruthenatetetrapropylammonium perruthenateTPAPR

名称和标识

数据登录号

维基百科标题

Tetrapropylammonium_perruthenate

CAS号

114615-82-6

MDL号

MFCD00074914

PubChem SID

248598832488906085240317

CompTox数据库

Gmelin ID

SureChEMBL数据库

CHEBI ID

数据登录号

化合物性质

理化性质

熔点

160 °C (decomposition)

~160 °C (dec.)(lit.)

160°C dec.

外观

Green solid

产品相关信息

纯度

97%

98%

线性分子式

(CH3CH2CH2)4NRuO4

级别

purum

化合物性质

分子相关蛋白质

暂无数据

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分子图谱

暂无数据

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描述信息

Sigma Aldrich

330744

Application
可溶、非挥发性、空气稳定的温和催化剂，可与适当的共氧化剂按化学计量或作为催化用途使用。
氧化剂，用于将 N,N′-二羟基咪唑啉转化为氮氧自由基。1将羟基取代的三-正丁基铵三氟硼酸盐氧化成醛和酮，而不会伴随碳-硼键的断裂。2,3
包装
1 g in glass bottle
250 mg in glass bottle

88126

Other Notes
催化剂，用于在二氯甲烷中于 N-甲基吗啉-N-氧化物 (NMO) 介导下将醇温和氧化成羰基化合物1

Wikipedia

Tetrapropylammonium_perruthenate

ChEBI

CHEBI:53209

A quaternary ammonium salt having tetrapropylammonium as the cation and perruthenate as the anion.

描述信息

参考文献

数据源提供

• For a brief feature on uses in synthesis, see: Synlett, 824 (2007).

• Selective, catalytic oxidant introduced by Ley. Normally used in combination with N-methylmorpholine-N-oxide as the stoichiometric reoxidant and 4A molecular sieves to remove water. Preferred solvents are dichloromethane and acetonitrile. Primary and secondary alcohols are oxidized to aldehydes and ketones in high yield: J. Chem. Soc., Chem. Commun., 1625 (1987). For an example of alcohol to aldehyde oxidation in the partial synthesis of the acyl tetronic acid ionophore tetronasin, see: Tetrahedron Lett., 35, 319 (1994). Also useful for a number of other oxidations such as lactols to lactones and sulfides to sulfones. For oxidation of secondary amines to imines, and of hydroxylamines to nitrones, see: Tetrahedron Lett., 35, 6567, 6571 (1994).

• For a comprehensive review of this reagent, see: Synthesis, 639 (1994). For a review of ruthenium oxo-complexes as organic oxidants, see: Chem. Soc. Rev., 21, 179 (1992).

参考文献

名称和标识

IUPAC传统名

tetrapropylammonium rutheniumoylolate TPAP

IUPAC标准名

tetrapropylazanium rutheniumoylolate

别名

数据登录号

维基百科标题

Tetrapropylammonium_perruthenate

CAS号

114615-82-6

MDL号

MFCD00074914

PubChem SID

248598832488906085240317

CompTox数据库

Gmelin ID

SureChEMBL数据库

CHEBI ID

描述信息

330744

88126

Other Notes
催化剂，用于在二氯甲烷中于 N-甲基吗啉-N-氧化物 (NMO) 介导下将醇温和氧化成羰基化合物1

Wikipedia

Tetrapropylammonium_perruthenate

ChEBI

CHEBI:53209

A quaternary ammonium salt having tetrapropylammonium as the cation and perruthenate as the anion.

参考文献

数据源提供

• For a brief feature on uses in synthesis, see: Synlett, 824 (2007).

• For a comprehensive review of this reagent, see: Synthesis, 639 (1994). For a review of ruthenium oxo-complexes as organic oxidants, see: Chem. Soc. Rev., 21, 179 (1992).

化合物性质

理化性质

熔点

160 °C (decomposition)

~160 °C (dec.)(lit.)

160°C dec.

外观

Green solid

产品相关信息

纯度

97%

98%

线性分子式

(CH3CH2CH2)4NRuO4

级别

purum

化合物信息

ID:129811