CAS 7791-03-9|LithoTab perchlorate ion|LITHIUM PERCHLORATE ACS REAGENT GRADE|lithium(1+) ion perchlorate|LITHIUM PERCHLORATE, ANHYDROUS|lithium(1+) ion perchlorate|Lithium perchlorate|Perchloric aci...

基本信息

化学结构

分子式

ClLiO₄

分子量

106.3916

精确质量

105.96451571

电荷

InChI

InChI=1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChIKey

MHCFAGZWMAWTNR-UHFFFAOYSA-M

Canonic Smiles

[O-][Cl](=O)(=O)=O.[Li+]

Isomeric Smiles

[Li+].[O-][Cl](=O)(=O)=O

计算属性

JChem

Acid pKa

-6.8919964

质子受体

质子供体

LogD (pH = 5.5)

-2.4740524

LogD (pH = 7.4)

-2.4740524

Log P

-0.097653694

摩尔折射率

11.9079

极化性

5.355259

极化表面积

74.27

可自由旋转的化学键

里宾斯基五规则

true

数据来源

名称和标识

IUPAC传统名

LithoTab perchlorate ion lithium(1+) ion perchlorate

别名

LITHIUM PERCHLORATE ACS REAGENT GRADELITHIUM PERCHLORATE, ANHYDROUSLithium perchloratePerchloric acid, lithium saltLithium Cloricum高氯酸锂Lithium perchlorate高氯酸锂溶液Lithium perchlorate solutionLithium perchlorate, anhydrous, ACS无水高氯酸锂, ACSLithium perchlorate, anhydrous高氯酸锂, 无水

IUPAC标准名

lithium(1+) ion perchlorate

名称和标识

数据登录号

CAS号

EC号

维基百科标题

Chemspider ID

PubChem CID

PubChem SID

2486703016208898324882632248822502485232024882249

MDL号

MFCD00011079

默克索引号

145539

数据登录号

化合物性质

分子相关蛋白质

暂无数据

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分子图谱

暂无数据

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描述信息

Wikipedia

Lithium_perchlorate

Sigma Aldrich

431567

General description
符合 ACS 的试剂规范。
包装
50, 250 g in poly bottle
Application
当用作助催化剂时，可加速 Baylis-Hillman 反应以及 α,β-不饱和羰基化合物与醛的偶联。1

634565

包装
10, 100 g in ampule

62579

Other Notes
An effective protein denaturant1,2
Physical form
powder or fine crystals

205281

包装
100, 500 g in poly bottle
5 g in glass bottle
Application
当用作助催化剂时，可加速 Baylis-Hillman 反应以及 α,β-不饱和羰基化合物与醛的偶联。1

MP Biomedicals

02194067

ACS Reagent Grade
Purity: 95%
NOT FOR EXPORT

描述信息

参考文献

PubChem文献

数据源提供

• The combination with an acyl anhydride is a powerful acylating agent for aromatic compounds under solvent-free conditions: Tetrahedron Lett., 43, 6331 (2002).

• Mild Lewis acid, often used as its diethyl ether complex; for a brief review of this reagent, see: Synlett, 649 (2002). The complex promotes formation of dithioacetals from aldehydes and dithiols: J. Org. Chem., 59, 4665 (1994), Michael additions of silyl enol ethers: J. Org. Chem., 60, 5024 (1995), and rearrangement of epoxides to carbonyl compounds, giving better selectivity than BF₃: J. Org. Chem., 61, 1877 (1996). Efficient catalyst for transesterification of ?-keto esters under near-neutral conditions: Synlett, 1338 (2001). Has been found to increase dramatically the rate of the Baylis-Hillman reaction (see 1,4-Diazabicyclo[2.2.2]octane, A14003): Tetrahedron Lett., 40, 1539 (1999). Catalyzes the Michael addition of amines to ɑ,?-unsaturated esters, nitriles, amides or ketones under solvent-free conditions: Tetrahedron, 60, 383 (2004). Efficient catalyst for siliylation of hydroxyl groups under solvent-free, neutral conditions: Organometallics, 23, 1457 (2004).

• See also Lithium trifluoromethanesulfonate, 39322.

参考文献

生物活性

PubChem BioAssay

生物活性

名称和标识

IUPAC传统名

LithoTab perchlorate ion lithium(1+) ion perchlorate

别名

IUPAC标准名

lithium(1+) ion perchlorate

数据登录号

CAS号

EC号

维基百科标题

Chemspider ID

PubChem CID

PubChem SID

2486703016208898324882632248822502485232024882249

MDL号

默克索引号

描述信息

431567

634565

包装
10, 100 g in ampule

62579

Other Notes
An effective protein denaturant1,2
Physical form
powder or fine crystals

205281

包装
100, 500 g in poly bottle
5 g in glass bottle
Application
当用作助催化剂时，可加速 Baylis-Hillman 反应以及 α,β-不饱和羰基化合物与醛的偶联。1

MP Biomedicals

02194067

ACS Reagent Grade
Purity: 95%
NOT FOR EXPORT

参考文献

PubChem文献

数据源提供

• The combination with an acyl anhydride is a powerful acylating agent for aromatic compounds under solvent-free conditions: Tetrahedron Lett., 43, 6331 (2002).

• See also Lithium trifluoromethanesulfonate, 39322.

生物活性

PubChem BioAssay

化合物性质

化合物信息

ID:105783