Substance
ID:739583
Names and Identifiers
IUPAC Traditional name
palladium(2+) ion dichloride
IUPAC name
palladium(2+) ion dichloride
Synonyms
氯化钯(II)Palladium(II) chloride
Properties
Safety Information
GHS Hazard statements
H314-H318-H290-H317-H303
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
GHS Precautionary statements
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
RTECS
RT3500000
Hazard Class
8
UN Number
UN3260
TSCA Listed
是
Risk Statements
41-43
Packing Group
III
European Hazard Symbols
Irritant (Xi)Safety Statements
24-26-37/39-60
Physical Property
Melting Point
675°C dec.
Solubility
Soluble in dilute mineral acids, aqueous metal halides
Density
4.0
Apperance
Crystalline
Product Information
Purity
99.9% (metals basis), Pd 59.5% min
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• In combination with benzoquinone as reoxidant, N-methylarylamines add to Michael acceptors to give enamines: J. Org. Chem., 46, 2561 (1981).
• For use in the microwave accelerated Heck coupling reaction of aryl halides in the ionic liquid 1-n-Butyl-3-methylimidazolium hexafluorophosphate, L19086, see: J. Org. Chem., 67, 6243 (2002).
• Terminal olefins can be oxygenated to ketones using a Cu(I) catalyst in the presence of a catalytic amount of PdCl2 (the Wacker process): Org. Synth. Coll., 7, 137 (1990). For an example in which the product is readily cyclized to give a useful terpenoid synthon, see: Org. Synth. Coll., 8, 208 (1993):
• In the presence of triphenylphosphine and MeLi, a Pd(0) species is generated which catalyzes the coupling of organolithium reagents with aryl or vinyl halides. For tabulated results, see: Org. Synth. Coll., 7, 172 (1990):
