CAS 7647-10-1|palladium(2+) ion dichloride|palladium(2+) ion dichloride|Palladium (II) chloride|氯化钯(II)|Palladium(II) chloride|Palladium(II) chloride, solution|氯化钯(II)溶液|氯化钯(II), Premion&...

General Information

Structure

Molecular Formula

Cl₂Pd

Molecular Mass

177.326

Exact Mass

175.84119136

Charge

InChI

InChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChIKey

PIBWKRNGBLPSSY-UHFFFAOYSA-L

Canonic Smiles

[Cl-].[Cl-].[Pd+2]

Isomeric Smiles

[Cl-].[Cl-].[Pd+2]

Calculated Properties

JChem

Acid pKa

-7.0

H Acceptors

H Donor

LogD (pH = 5.5)

0.8327582

LogD (pH = 7.4)

0.8327582

Log P

0.6123387

Molar Refractivity

5.6156

Polarizability

2.1090326

Polar Surface Area

0.0

Rotatable Bonds

Lipinski's Rule of Five

true

Data Source

Academic Data

Commercial Catalog

Data Source

Names and Identifiers

IUPAC name

palladium(2+) ion dichloride

IUPAC Traditional name

palladium(2+) ion dichloride

Synonyms

Palladium (II) chloridePalladium(II) chloride氯化钯(II)Palladium(II) chloride, solution氯化钯(II)溶液氯化钯(II), Premion®Palladium(II) chloride, Premion®

Names and Identifiers

Registration numbers

EC Number

Merck Index

CAS Number

MDL Number

PubChem CID

PubChem SID

Registration numbers

Properties

Product Information

99%

99.9% (metals basis), Pd 59.5% min

Pd 9.0-11.0% w/w (cont. Pd)

Pd 20-25% w/w (cont. Pd)

99.999% (metals basis), Pd 59.5% min

Properties

Related Proteins

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Molecular Spectra

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Molecule Details

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References

PubChem Literature

From Data Sources

• In combination with benzoquinone as reoxidant, N-methylarylamines add to Michael acceptors to give enamines: J. Org. Chem., 46, 2561 (1981).

• For use in the microwave accelerated Heck coupling reaction of aryl halides in the ionic liquid 1-n-Butyl-3-methylimidazolium hexafluorophosphate, L19086, see: J. Org. Chem., 67, 6243 (2002).

• Terminal olefins can be oxygenated to ketones using a Cu(I) catalyst in the presence of a catalytic amount of PdCl₂ (the Wacker process): Org. Synth. Coll., 7, 137 (1990). For an example in which the product is readily cyclized to give a useful terpenoid synthon, see: Org. Synth. Coll., 8, 208 (1993):

• In the presence of triphenylphosphine and MeLi, a Pd(0) species is generated which catalyzes the coupling of organolithium reagents with aryl or vinyl halides. For tabulated results, see: Org. Synth. Coll., 7, 172 (1990):