Substance
ID:716775
Names and Identifiers
IUPAC name
tetrabutylazanium hydrogen sulfate
IUPAC Traditional name
tetrabutylammonium hydrogensulfate
Synonyms
正四丁基硫酸氢基铵Tetra-n-butylammonium hydrogen sulfate
Properties
Safety Information
GHS Precautionary statements
P261-P301+P310-P305+P351+P338-P302+P352-P405-P501A
TSCA Listed
是
European Hazard Symbols
Harmful (X)Risk Statements
22-36/37/38
Safety Statements
26-36/37
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
GHS Hazard statements
H301-H315-H319-H335
Physical Property
Melting Point
168-172°C
Product Information
Purity
97%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• For phase-transfer catalyzed conversion of nitriles to amides by alkaline H2O2, see: Synthesis, 243 (1980).
• Benzanilides have been N-alkylated in the presence of NaOH and K2CO3: Synth. Commun., 18, 2011 (1988).
• For use in the permanganate oxidation of benzylic positions, see Potassium permanganate, A12170.
• It was the most effective catalyst studied for the cyclization of ?-amino acids to ?-lactams by methanesulfonyl chloride and KHCO3: Chem. Lett., 443 (1981).
• Widely used phase-transfer catalyst; see Appendix 2. Some illustrative applications are given below:
• The oxidation of primary alcohols to aldehydes by potassium chromate under phase-transfer conditions is better for higher homologues, where solubility in the aqueous phase is limited: Synthesis, 134 (1979). For phase-transfer catalyzed dichromate oxidation of secondary alcohols to ketones, see: Tetrahedron Lett., 1601 (1978).
• In the dehydrohalogenation of aryl 2-haloethyl ethers to give vinyl ethers, this catalyst was found much more effective than the corresponding halides or benzyltriethylammonium salts: Synthesis, 688 (1979).