Substance
ID:716511
Names and Identifiers
IUPAC name
2-methoxypyridine
IUPAC Traditional name
2-methoxypyridine
Synonyms
2-Methoxypyridine2-甲氧基吡啶Methyl 2-pyridyl ether
Registration numbers
Beilstein Number
EC Number
MDL Number
CAS Number
Properties
Safety Information
UN Number
UN3271
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Hazard Class
3
Packing Group
III
Risk Statements
10-36/37/38
GHS Hazard statements
H226-H315-H319-H335
TSCA Listed
否
European Hazard Symbols
Irritant (Xi)GHS Precautionary statements
P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
Safety Statements
26-37
Physical Property
Density
1.046
Flash Point
32°C(89°F)
Refractive Index
1.5040
Boiling Point
142-143°C
Product Information
Purity
98%
Molecule Details
No Data Available
Click here to submit data
Molecular Spectra
No Data Available
Click here to submit data
References
• Can be metallated at the 3-position with LDA at -70o: J. Org. Chem., 53, 1367 (1988). With the unimetal superbase complex formed from 2 mol of n-BuLi and I mol of 2-(Dimethylamino)ethanol, B23616, in hexane, products are obtained resulting from apparent metallation at the 6-position. A radical mechanism, rather than a true 6-metallation, has been proposed for this reaction: J. Chem. Soc., Perkin 1, 3071 (1997). Analogous results have been reported with 2-chloropyridine: Org. Lett., 2, 803 (2000).