Substance
ID:716223
Names and Identifiers
IUPAC name
benzyltriethylazanium chloride
IUPAC Traditional name
benzyltriethylazanium chloride
Synonyms
Benzyltriethylammonium chlorideBTEACTEBA三乙基苄基氯化铵
Registration numbers
MDL Number
CAS Number
EC Number
Beilstein Number
Properties
Product Information
Purity
99%
Safety Information
Risk Statements
36/37/38
Safety Statements
26-37
TSCA Listed
是
GHS Precautionary statements
P261-P305+P351+P338-P302+P352-P321-P405-P501A
Storage Warning
Hygroscopic
GHS Pictograms
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
GHS Hazard statements
H315-H319-H335
European Hazard Symbols
Irritant (Xi)RTECS
BO8275000
Physical Property
Melting Point
ca 190°C dec.
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• For use in the formation of polysubstituted cyclopropanes by carbene-type addition to double bonds, see Ethyl chloroacetate, A15554.
• For use in the dialkylation of malonate esters to give cyclopropane derivatives, see: Synthesis, 54 (1985); Org. Synth. Coll., 7, 411 (1993).
• Phase-transfer catalyst (see Appendix 2) which has found wide application in the generation of carbenes from haloforms and related precursors: Org. Synth. Coll., 7, 12 (1990); 8, 223 (1993). Dihalocarbenes have been used to convert primary amines (t-butylamine) to isonitriles: Org. Synth. Coll., 6, 232 (1988), and in the dehydration of amides, thioamides and oximes to nitriles: Tetrahedron Lett., 2121 (1973). Ureas give cyanamides.
• In combination with NaBr in acetonitrile, has been used for the mono-dealkylation of phosphonate diesters: Synthesis, 453 (1983).