Substance
ID:715286
Names and Identifiers
IUPAC Traditional name
chloromethyl 2,2-dimethylpropanoate
IUPAC name
chloromethyl 2,2-dimethylpropanoate
Synonyms
Pivaloyloxymethyl chlorideChloromethyl pivalateChloromethyl trimethylacetate新戊酸氯甲酯
Registration numbers
EC Number
CAS Number
MDL Number
Beilstein Number
Properties
Safety Information
Safety Statements
26-36/37/39-45
GHS Pictograms
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures
Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
UN Number
UN2924
Risk Statements
10-34
GHS Hazard statements
H314-H318-H226
GHS Precautionary statements
P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
Packing Group
III
Hazard Class
3
TSCA Listed
是
European Hazard Symbols
Corrosive (C)Physical Property
Flash Point
40°C(104°F)
Density
1.045
Boiling Point
146-148°C
Refractive Index
1.4170
Product Information
Purity
97%
Molecule Details
No Data Available
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Molecular Spectra
No Data Available
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References
• Reagent for the N-protection of amines, e.g. adenine in the presence of K2CO3 in DMF, as pivaloyloxymethyl (Pom) derivatives, which have been found useful in the synthesis of sensitive nucleosides. The Pom group is cleaved in mild base, e.g. methanolic ammonia: J. Am. Chem. Soc., 89, 5439 (1967).