CAS 7783-99-5|silver(1+) ion nitrite|亚硝酸银|Silver nitrite|silver(1+) ion nitrite

General Information

Structure

Molecular Formula

AgNO₂

Molecular Mass

153.8737

Exact Mass

152.89800025

Charge

InChI

InChI=1S/Ag.HNO2/c;2-1-3/h;(H,2,3)/q+1;/p-1

InChIKey

KKKDGYXNGYJJRX-UHFFFAOYSA-M

Canonic Smiles

[O-]N=O.[Ag+]

Isomeric Smiles

N(=O)[O-].[Ag+]

Calculated Properties

JChem

Acid pKa

3.3200002

H Acceptors

H Donor

LogD (pH = 5.5)

0.16613764

LogD (pH = 7.4)

0.16613764

Log P

0.16613764

Molar Refractivity

7.6

Polarizability

2.4691868

Polar Surface Area

52.49

Rotatable Bonds

Lipinski's Rule of Five

true

Data Source

Commercial Catalog

Academic Data

Data Source

Names and Identifiers

IUPAC name

silver(1+) ion nitrite

Synonyms

亚硝酸银Silver nitrite

IUPAC Traditional name

silver(1+) ion nitrite

Names and Identifiers

Registration numbers

MDL Number

MFCD00003413

EC Number

232-041-7

CAS Number

7783-99-5

PubChem SID

248883212487880224853618162226378

PubChem CID

160904

Merck Index

148519

Registration numbers

Properties

Related Proteins

No Data Available

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Molecular Spectra

No Data Available

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Molecule Details

Sigma Aldrich

227188

Packaging
10, 50 g in glass bottle

545015

Packaging
5, 25 g in glass bottle

Molecule Details

References

PubChem Literature

From Data Sources

• Forms complexes with alkenes, used in the separation of mixtures; see, e.g.: Org. Synth. Coll., 5, 315 (1973).

• For a brief feature on uses of the reagent in synthesis, see: Synlett, 3016 (2005).

• Promotes the reactivity of NCS in the cleavage of 2-acylated 1,3-dithianes: Synthesis, 17 (1969), and of NBS in the 1-bromination of terminal alkynes: Angew. Chem. Int. Ed., 23, 727 (1984).

• The Hunsdiecker reaction of Ag salts of carboxylic acids with Br₂ provides alkyl bromides with one less carbon atom which is lost as CO₂; see, e.g.: Org. Synth. Coll., 3, 578 (1955). Reviews: Chem. Rev., 56, 219 (1956); Org. React., 9, 332 (1957). Compare also Mercury(II) oxide, A16157.

• In combination with Br₂ or I₂ in refluxing methanol, brings about the rearrangement of acetophenones to methyl arylacetates, a reaction previously induced by thallium(III) nitrate: J. Chem. Soc., Perkin 1, 235 (1982):

• For the alkylation of substrates by radicals derived from decarboxylation of acids, see Trimethylacetic acid, A10776.

References

Bioactivity

PubChem BioAssay

Bioactivity

Data Source

Commercial Catalog

Academic Data

Names and Identifiers

IUPAC name

silver(1+) ion nitrite

Synonyms

亚硝酸银Silver nitrite

IUPAC Traditional name

silver(1+) ion nitrite

Registration numbers

MDL Number

MFCD00003413

EC Number

232-041-7

CAS Number

7783-99-5

PubChem SID

248883212487880224853618162226378

PubChem CID

160904

Merck Index

148519

Molecule Details

Sigma Aldrich

227188

Packaging
10, 50 g in glass bottle

545015

Packaging
5, 25 g in glass bottle

References

PubChem Literature

From Data Sources

• Forms complexes with alkenes, used in the separation of mixtures; see, e.g.: Org. Synth. Coll., 5, 315 (1973).

• For a brief feature on uses of the reagent in synthesis, see: Synlett, 3016 (2005).

• Promotes the reactivity of NCS in the cleavage of 2-acylated 1,3-dithianes: Synthesis, 17 (1969), and of NBS in the 1-bromination of terminal alkynes: Angew. Chem. Int. Ed., 23, 727 (1984).

• For the alkylation of substrates by radicals derived from decarboxylation of acids, see Trimethylacetic acid, A10776.

Bioactivity

PubChem BioAssay

Properties

Molecule

ID:132101