CAS 7791-03-9|LithoTab perchlorate ion|LITHIUM PERCHLORATE ACS REAGENT GRADE|lithium(1+) ion perchlorate|LITHIUM PERCHLORATE, ANHYDROUS|lithium(1+) ion perchlorate|Lithium perchlorate|Perchloric aci...

General Information

Structure

Molecular Formula

ClLiO₄

Molecular Mass

106.3916

Exact Mass

105.96451571

Charge

InChI

InChI=1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChIKey

MHCFAGZWMAWTNR-UHFFFAOYSA-M

Canonic Smiles

[O-][Cl](=O)(=O)=O.[Li+]

Isomeric Smiles

[Li+].[O-][Cl](=O)(=O)=O

Calculated Properties

JChem

Acid pKa

-6.8919964

H Acceptors

H Donor

LogD (pH = 5.5)

-2.4740524

LogD (pH = 7.4)

-2.4740524

Log P

-0.097653694

Molar Refractivity

11.9079

Polarizability

5.355259

Polar Surface Area

74.27

Rotatable Bonds

Lipinski's Rule of Five

true

Data Source

Names and Identifiers

IUPAC Traditional name

LithoTab perchlorate ion lithium(1+) ion perchlorate

Synonyms

LITHIUM PERCHLORATE ACS REAGENT GRADELITHIUM PERCHLORATE, ANHYDROUSLithium perchloratePerchloric acid, lithium saltLithium Cloricum高氯酸锂Lithium perchlorate高氯酸锂溶液Lithium perchlorate solutionLithium perchlorate, anhydrous, ACS无水高氯酸锂, ACSLithium perchlorate, anhydrous高氯酸锂, 无水

IUPAC name

lithium(1+) ion perchlorate

Names and Identifiers

Registration numbers

CAS Number

EC Number

Wikipedia Title

Chemspider ID

PubChem CID

PubChem SID

2486703016208898324882632248822502485232024882249

MDL Number

MFCD00011079

Merck Index

145539

Registration numbers

Properties

Related Proteins

No Data Available

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Molecular Spectra

No Data Available

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Molecule Details

Wikipedia

Lithium_perchlorate

Sigma Aldrich

431567

General description
Meets ACS reagent specifications.
Packaging
50, 250 g in poly bottle
Application
When used as a co-catalyst, accelerates the Baylis-Hillman reaction, the coupling of α,β-unsaturated carbonyls with aldehydes.1

634565

Packaging
10, 100 g in ampule

62579

Other Notes
An effective protein denaturant1,2
Physical form
powder or fine crystals

205281

Packaging
100, 500 g in poly bottle
5 g in glass bottle
Application
When used as a co-catalyst, accelerates the Baylis-Hillman reaction, the coupling of α,β-unsaturated carbonyls with aldehydes.1

MP Biomedicals

02194067

ACS Reagent Grade
Purity: 95%
NOT FOR EXPORT

Molecule Details

References

PubChem Literature

From Data Sources

• See also Lithium trifluoromethanesulfonate, 39322.

• Mild Lewis acid, often used as its diethyl ether complex; for a brief review of this reagent, see: Synlett, 649 (2002). The complex promotes formation of dithioacetals from aldehydes and dithiols: J. Org. Chem., 59, 4665 (1994), Michael additions of silyl enol ethers: J. Org. Chem., 60, 5024 (1995), and rearrangement of epoxides to carbonyl compounds, giving better selectivity than BF₃: J. Org. Chem., 61, 1877 (1996). Efficient catalyst for transesterification of ?-keto esters under near-neutral conditions: Synlett, 1338 (2001). Has been found to increase dramatically the rate of the Baylis-Hillman reaction (see 1,4-Diazabicyclo[2.2.2]octane, A14003): Tetrahedron Lett., 40, 1539 (1999). Catalyzes the Michael addition of amines to ɑ,?-unsaturated esters, nitriles, amides or ketones under solvent-free conditions: Tetrahedron, 60, 383 (2004). Efficient catalyst for siliylation of hydroxyl groups under solvent-free, neutral conditions: Organometallics, 23, 1457 (2004).

• The combination with an acyl anhydride is a powerful acylating agent for aromatic compounds under solvent-free conditions: Tetrahedron Lett., 43, 6331 (2002).

References

Bioactivity

PubChem BioAssay

Bioactivity

Names and Identifiers

IUPAC Traditional name

LithoTab perchlorate ion lithium(1+) ion perchlorate

Synonyms

IUPAC name

lithium(1+) ion perchlorate

Registration numbers

CAS Number

EC Number

Wikipedia Title

Chemspider ID

PubChem CID

PubChem SID

2486703016208898324882632248822502485232024882249

MDL Number

Merck Index

Molecule Details

431567

634565

Packaging
10, 100 g in ampule

62579

Other Notes
An effective protein denaturant1,2
Physical form
powder or fine crystals

205281

Packaging
100, 500 g in poly bottle
5 g in glass bottle
Application
When used as a co-catalyst, accelerates the Baylis-Hillman reaction, the coupling of α,β-unsaturated carbonyls with aldehydes.1

MP Biomedicals

02194067

ACS Reagent Grade
Purity: 95%
NOT FOR EXPORT

References

PubChem Literature

From Data Sources

• See also Lithium trifluoromethanesulfonate, 39322.

• The combination with an acyl anhydride is a powerful acylating agent for aromatic compounds under solvent-free conditions: Tetrahedron Lett., 43, 6331 (2002).

Bioactivity

PubChem BioAssay

Properties

Molecule

ID:105783