CAS 100-63-0|PHENYLHYDRAZINE|phenylhydrazine|phenylhydrazine|Hydrazinobenzene|苯肼|Phenylhydrazine|Monophenylhydrazine|Phenyldiazane|Hydrazinobenzene|PhNHNH2|Phenylhydrazin|hydrazobenzene|1-PHENYLHY...

PHENYLHYDRAZINEHydrazinobenzene苯肼PhenylhydrazineMonophenylhydrazinePhenyldiazaneHydrazinobenzenePhNHNH2Phenylhydrazinhydrazobenzene1-PHENYLHYDRAZINEmonophenylhydrazinePhenylhydrazinephenylhydrazine

IUPAC name

phenylhydrazine

IUPAC Traditional name

phenylhydrazine

Names and Identifiers

Registration numbers

EC Number

CAS Number

CHEMBL

KEGG ID

Wikipedia Title

Chemspider ID

CHEBI ID

27924CHEBI:27924CHEBI:25995CHEBI:8099CHEBI:44985

PubChem CID

7516

Beilstein Number

606080

PubChem SID

24898342162091326248871532488715426697042

MDL Number

MFCD00007573

Merck Index

147293

BRENDA Database

5.1.1.131.7.2.64.1.1.361.11.1.132.6.1.704.3.1.156.1.1.161.4.9.22.6.1.62.3.1.54.1.1.933.5.5.14.3.1.192.6.1.622.6.1.41.1.3.155.4.3.34.1.2.262.6.1.554.4.1.133.5.1.62.3.1.293.5.99.52.1.2.14.8.1.21.5.3.151.1.1.1693.5.1.872.3.2.93.5.5.75.1.1.11.5.8.23.5.5.51.14.13.81.5.3.11.2.3.44.1.1.503.5.99.111.17.3.21.7.2.11.14.13.1052.3.2.23.5.1.41.1.1.282.1.1.32.6.1.133.5.1.912.5.1.494.5.1.21.2.3.11.5.99.124.6.1.22.6.1.212.6.1.1135.1.1.151.4.3.214.2.1.493.5.1.1011.11.1.194.4.1.13.5.4.41.1.1.291.1.3.42.6.1.371.4.3.22.6.1.74.4.1.152.6.1.21.1.3.94.1.1.924.1.1.571.11.1.73.1.1.834.3.1.22.6.1.54.2.1.844.3.1.181.1.1.261.1.3.394.1.2.493.5.2.141.4.3.192.6.1.192.5.1.483.5.3.95.4.3.64.3.1.31.5.99.62.6.1.451.2.2.B12.6.1.573.5.1.764.1.1.194.2.1.281.14.12.171.13.11.881.4.9.11.14.18.14.1.1.111.1.3.132.6.1.232.6.1.422.7.3.12.3.2.B31.4.3.41.21.4.12.3.1.474.1.1.641.17.1.51.4.3.131.4.3.224.1.3.12.5.1.47

EnzymePortal Database

Q10725Q68AP4P0A790P84888P84887P0C7I4C3K630P83989Q76KX0Q7XSN8P50651

UniProt Database

Q76KX0O82872P0C7I4Q7XSN8P50651P83989P86491Q68AP4P0A790Q75SP7P84888Q10725C3K630P84887

BindingDB Database

SureChEMBL Database

MetaCyc Database

BKMS React Database

Reaxys Registry

PubMed Citation Links

71444472058585319627281

Patent number

WO2006137083US2007197580EP1408035WO2006102758US2005159424EP1760078WO2007105203US2006058373US2008275092EP1889834US2007185115EP0937714WO2006092032EP1083171US2005000034

BRENDA Ligand Database

16737139252

CompTox Database

DTXSID8021147

MetaboLights Database

SABIO-RK Database

Gmelin ID

NMRShiftDB Database

ACToR Database

Protein Data Bank

PDBeChem Database

Registration numbers

Properties

Related Proteins

PDB Bank

4N4M

2AGL

Related Proteins

Molecular Spectra

No Data Available

Click here to submit data

Molecule Details

MP Biomedicals

02151837

Free Base Used as N-protecting reagent and for cleavage of phthaloyl group. 1 ml = approx. 1.10 g

05217394

MP Biomedicals Rare Chemical collection

Wikipedia

Phenylhydrazine

Sigma Aldrich

P26252

Packaging
5, 100, 500 g in glass bottle

78670

Application
for spectrophotometric determination of Al, Cr, Mo, Ti, Zr

TRC

P335075

An aryl hydrazine used in the preparation of various dyes and pharmaceutical compounds. It is used in the investigation of oligosaccharides as well as the structure of photosystem II.

ChEBI

CHEBI:27924

A phenylhydrazine that is the monophenyl derivative of hydrazine.

Molecule Details

References

PubChem Literature

From Data Sources

• Lattova, E. et al.: Meth. Mol. Biol., 534, 65 (2009)

• Anderson, L.B. et al.: J. Biol. Chem., 275, 4920 (2009)

• Derivatizing agent for the conversion of carbonyl compounds to their phenylhydrazones best known as intermediates in the Fischer indole synthesis, by cyclization under acidic conditions with loss of ammonia. The classical reagent is anhydrous ZnCl₂: Org. Synth. Coll., 3, 725 (1976). For reviews, see: Chem. Rev., 63, 373 (1963); 69, 227 (1969); Tetrahedron, 36, 161 (1980); Org. Prep. Proced. Int., 25,609 (1993). Milder cyclization conditions are sometimes effective, e.g.: dilute H₂SO₄: J. Org. Chem., 59, 3738 (1994); PCl₃: J. Chem. Soc., Chem. Commun., 563 (1981); Tetrahedron, 41, 4615 (1985). Cyclohexanone phenylhydrazone gives tetrahydrocarbazole on heating in acetic acid: Org. Synth. Coll., 4, 884 (1963).

• Methods used for the cleavage of phenylhydrazones include exchange by refluxing with acetone: J. Org. Chem., 40, 3302 (1975), or oxidative cleavage by Fe(NO₃)₃ on a clay support: Synthesis, 439 (1985).

References

Bioactivity

PubChem BioAssay

Bioactivity

Molecule

ID:103452