物质信息
ID:740837
名称和标识
IUPAC标准名
zinc(2+) ion bis(iminomethanide)
IUPAC传统名
zinc(2+) ion bis(cyanide)
别名
氰化锌Zinc cyanide
化合物性质
理化性质
溶解度
Insoluble in water, alcohol. Soluble in solutions of alkali cyanides or hydroxides
密度
1.852
熔点
800°C dec.
外观
Crystalline
安全信息
联合国危险货物包装类别(PG)
I
安全公开号
7-28-29-45-60-61
GHS危险品标识
对水环境的危害
急性危害，类别1
慢性危害，类别1,2
急性毒性（口服，皮肤接触，吸入），类别1,2,3
联合国危险货物编号
UN1713
欧盟危险性物质标志
环境危害性 (N)
剧毒 (T+)保存注意事项
Hygroscopic
危险公开号
26/27/28-32-50/53
联合国危险货物等级
6.1
RTECS编号
ZH1575000
TSCA收录
是
GHS危险声明
H300-H310-H330-H400-H410
GHS警示性声明
P260-P301+P310-P304+P340-P320-P330-P361-P405-P501A
产品相关信息
纯度
85%
描述信息
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分子图谱
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参考文献
• For an example of the Adams modification of the Gattermann reaction for formylation of aromatics, see: Org. Synth. Coll., 3, 549 (1955). For in situ cyanosilylation of aldehydes and ketones with Zn(CN)2 and TMS chloride, as an alternative to Trimethylsilyl cyanide, A19598, see: Org. Synth. Coll., 7, 521 (1990).
• Used in combination with a Pd(0) catalyst in improved procedures for the cyanation of aromatic halides, instead of the classical Rosenmund-Von Braun (CuCN) method: Synth. Commun., 24, 557 (1994); Tetrahedron Lett., 40, 8193 (1999); 41, 3271 (2000); 45, 1441 (2004). For cyanation of aryl triflates, see: Tetrahedron Lett., 39, 2907 (1998); Synlett, 1207 (1998). For a review of palladium- and copper-catalyzed cyanations, see: Eur. J. Inorg. Chem., 3513 (2003).