物质信息
ID:739962
名称和标识
别名
Copper(I) bromide溴化亚铜(I)
IUPAC标准名
λ1-copper(1+) ion bromide
IUPAC传统名
λ1-copper(1+) ion bromide
化合物性质
理化性质
密度
4.98
溶解度
Slightly soluble in cold water. Decomposes in hot water. Soluble in HBr, HCl, NH4OH
沸点
1345°C
外观
Powder
熔点
492°C
安全信息
GHS危险声明
H315-H319-H335
安全公开号
26-37
GHS警示性声明
P261-P305+P351+P338-P302+P352-P321-P405-P501A
保存注意事项
Air Sensitive
欧盟危险性物质标志
刺激性 (Xi)危险公开号
36/37/38
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
TSCA收录
是
产品相关信息
纯度
98%
描述信息
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分子图谱
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参考文献
• Catalyst for 1,4-addition of Grignard reagents to enones: J. Org. Chem., 27, 707 (1962); Org. Synth. Coll., 8, 522 (1993).
• Reaction of Grignard reagents with aromatic nitriles is potentially a useful route to ketones via the imine. However, in the absence of a catalyst, reaction is generally very slow and gives indifferent yields. In the presence of CuBr, tert-butylmagnesium chloride reacts readily with benzonitrile to give tert-butyl phenyl ketone in 94% yield: J. Org. Chem., 52, 3901 (1987).
• Precursor of organocopper reagents. For reviews, see: Org. React., 22, 253 (1975); 41, 135 (1992); Synthesis, 63 (1972); Tetrahedron, 45, 349 (1989).