物质信息
ID:739583
名称和标识
IUPAC传统名
palladium(2+) ion dichloride
IUPAC标准名
palladium(2+) ion dichloride
别名
氯化钯(II)Palladium(II) chloride
化合物性质
安全信息
GHS危险声明
H314-H318-H290-H317-H303
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
腐蚀金属，类别1
腐蚀皮肤，类别1A，1B，1C
严重眼损伤，类别1
GHS警示性声明
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
RTECS编号
RT3500000
联合国危险货物等级
8
联合国危险货物编号
UN3260
TSCA收录
是
危险公开号
41-43
联合国危险货物包装类别(PG)
III
欧盟危险性物质标志
刺激性 (Xi)安全公开号
24-26-37/39-60
理化性质
熔点
675°C dec.
溶解度
Soluble in dilute mineral acids, aqueous metal halides
密度
4.0
外观
Crystalline
产品相关信息
纯度
99.9% (metals basis), Pd 59.5% min
描述信息
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分子图谱
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参考文献
• In combination with benzoquinone as reoxidant, N-methylarylamines add to Michael acceptors to give enamines: J. Org. Chem., 46, 2561 (1981).
• For use in the microwave accelerated Heck coupling reaction of aryl halides in the ionic liquid 1-n-Butyl-3-methylimidazolium hexafluorophosphate, L19086, see: J. Org. Chem., 67, 6243 (2002).
• Terminal olefins can be oxygenated to ketones using a Cu(I) catalyst in the presence of a catalytic amount of PdCl2 (the Wacker process): Org. Synth. Coll., 7, 137 (1990). For an example in which the product is readily cyclized to give a useful terpenoid synthon, see: Org. Synth. Coll., 8, 208 (1993):
• In the presence of triphenylphosphine and MeLi, a Pd(0) species is generated which catalyzes the coupling of organolithium reagents with aryl or vinyl halides. For tabulated results, see: Org. Synth. Coll., 7, 172 (1990):
