物质信息
ID:720925
名称和标识
IUPAC传统名
1-azabicyclo 2.2.2 octan-3-ol
IUPAC标准名
1-azabicyclo[2.2.2]octan-3-ol
别名
1-Azabicyclo[2.2.2]octan-3-ol3-Hydroxyquinuclidine3-Quinuclidinol3-喹核醇
化合物性质
理化性质
熔点
217-224°C
安全信息
GHS危险品标识
腐蚀金属，类别1
腐蚀皮肤，类别1A，1B，1C
严重眼损伤，类别1
联合国危险货物编号
UN3263
GHS危险声明
H314-H318
GHS警示性声明
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
联合国危险货物等级
8
欧盟危险性物质标志
腐蚀性 (C)保存注意事项
Air Sensitive
TSCA收录
是
危险公开号
34
安全公开号
26-36/37/39-45
RTECS编号
VD6191700
联合国危险货物包装类别(PG)
III
产品相关信息
纯度
98+%
描述信息
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分子图谱
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参考文献
• Superior catalyst for the Baylis-Hillman reaction: the addition of acrylic esters to aldehydes, often very slow (4-7 days) with the usual catalyst 1,4-Diazabicyclo[2.2.2]octane, A14003, is much faster (<1 day) in the presence of quinuclidinol: Synth. Commun., 18, 495 (1988); Tetrahedron Lett., 32, 5611 (1991). For more recent discussion and methodology, see: J. Org. Chem., 67, 510 (2002); 68, 692 (2003). For reviews of the Baylis-Hillman reaction, see: Tetrahedron, 44, 4653 (1988); 52, 8001 (1996). The rate of addition of enones to aldehydes is similarly enhanced: Synth. Commun., 18, 495 (1988); 19, 959 (1989).
• Reagent for selective cleavage of ?-keto esters to ketones in high yield: Synth. Commun., 5, 341 (1975). Geminal diesters are converted to monoesters in high yield under similar conditions: J. Org. Chem., 41, 208 (1976).