物质信息
ID:720082
名称和标识
IUPAC标准名
copper(2+) ion ditrifluoromethanesulfonate
别名
Copper(II) triflateTrifluoromethanesulfonic acid copper(II) salt三氟甲烷磺酸铜(II)Copper(II) trifluoromethanesulfonate
IUPAC传统名
copper(2+) ion ditriflate
化合物性质
产品相关信息
纯度
98%
安全信息
欧盟危险性物质标志
腐蚀性 (C)安全公开号
20-26-36/37/39-45-60
危险公开号
34
GHS危险品标识
腐蚀金属，类别1
腐蚀皮肤，类别1A，1B，1C
严重眼损伤，类别1
GHS危险声明
H314-H318
保存注意事项
Hygroscopic
TSCA收录
否
联合国危险货物等级
8
联合国危险货物编号
UN3261
GHS警示性声明
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
联合国危险货物包装类别(PG)
III
理化性质
熔点
dec.
描述信息
暂无数据
点击上传数据
分子图谱
暂无数据
点击上传数据
参考文献
• Mild Lewis acid:
• For a brief feature on uses of the reagent in synthesis, see: Synlett, 1044 (2005).
• Widely used to generate carbenoid species from ɑ-diazo esters and ketones, via in situ reduction to the Cu(I) species: J. Am. Chem. Soc., 95, 3300 (1973). Preferred reagent for intramolecular cyclization of various diazo ketones: J. Org. Chem., 49, 11496 (1984). Also promotes the reaction between diazo esters and imines to give aziridines: J. Chem. Soc., Chem. Commun., 1 (1995).
• Catalyzes syn-selective aldol condensation of (Z)-silyl enol ethers with aldehydes: Chem. Lett., 959 (1997).
• Used catalytically, promotes dehydration of alcohols and diols to alkenes at ambient temperatures: Helv. Chim. Acta, 70, 607 (1987).
• Friedel-Crafts alkylation and acylation reactions of aromatics are also catalyzed: Tetrahedron, 57, 241 (2001).