物质信息
ID:719844
名称和标识
IUPAC标准名
2-amino-2,3-dihydro-1H-isoindole-1,3-dione
IUPAC传统名
2-aminoisoindole-1,3-dione
别名
N-AminophthalimideN-氨基邻苯二甲酰亚胺
化合物性质
安全信息
GHS危险声明
H315-H319-H335
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
安全公开号
26-36
GHS警示性声明
P261-P305+P351+P338-P302+P352-P321-P405-P501A
欧盟危险性物质标志
刺激性 (Xi)TSCA收录
否
危险公开号
36/37/38
产品相关信息
纯度
94%
理化性质
熔点
ca 195°C dec.
描述信息
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分子图谱
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参考文献
• Aziridination has also been achieved in high yield by electrochemical oxidation: J. Am. Chem. Soc., 124, 530 (2002).
• May be oxidized with lead(IV) acetate to "phthalimidonitrene", which adds to alkenes to give aziridines. The phthalimido group can be cleaved with hydrazine hydrate: J. Chem. Soc. (C), 576 (1970); J. Am. Chem. Soc., 92, 1784 (1970); Helv. Chim. Acta,55, 1276 (1972); Org. Synth. Coll., 6, 56 (1988). Addition to cyclopentadienes leads to substituted pyridines after ring-opening with base: Heterocycles, 22, 1369 (1984). Addition to the (racemic) acrylic ester below shows an extremely high facial selectivity, adding to the less hindered side (290:1): Helv. Chim. Acta, 72, 1095 (1989).
