物质信息
ID:717766
名称和标识
IUPAC标准名
tetrabutylazanium iodide
IUPAC传统名
tetrabutylammonium iodide
别名
Tetra-n-butylammonium iodide四正丁基碘化铵
化合物性质
安全信息
GHS危险声明
H301-H315-H319-H335
GHS警示性声明
P261-P301+P310-P305+P351+P338-P302+P352-P405-P501A
RTECS编号
BS5450000
危险公开号
22-36/37/38
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别1,2,3
欧盟危险性物质标志
有害性 (X)安全公开号
26-36/37
保存注意事项
Light Sensitive & Hygroscopic
TSCA收录
是
产品相关信息
纯度
98%
理化性质
熔点
142-148°C
描述信息
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分子图谱
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参考文献
• Aliphatic and aromatic sulfonic acids are reduced to thiols in the presence of trifluoroacetic anhydride, followed by hydrolysis of the resulting trifluoroacetates: Tetrahedron Lett., 21, 1235 (1980).
• Useful source of I- for nucleophilic displacements, e.g. in the formation of neopentyl iodides from the triflates: J. Org. Chem., 45, 4387 (1980).
• Catalyst for the high-yield methylation of alcohols with dimethyl sulfate: Angew. Chem., 85, 868; Angew. Chem. Int. Ed., 12, 846 (1973), or the benzylation of alcohols with benzyl bromide in organic solvents: Org. Synth. Coll., 8, 34 (1993); 9, 52 (1998).
• In combination with Boron trifluoride diethyl etherate, A15275, has been used in a mild, versatile cleavage of ethers: Synthesis, 274 (1985).