物质信息
ID:717595
名称和标识
IUPAC标准名
1-(bromomethyl)-4-nitrobenzene
别名
alpha-Bromo-4-nitrotoluene4-Nitrobenzyl bromide4-硝基溴苄
IUPAC传统名
nitrobenzyl bromide
化合物性质
产品相关信息
纯度
97+%
安全信息
欧盟危险性物质标志
腐蚀性 (C)联合国危险货物包装类别(PG)
II
危险公开号
34
RTECS编号
XS7967000
GHS警示性声明
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
TSCA收录
是
GHS危险品标识
腐蚀金属，类别1
腐蚀皮肤，类别1A，1B，1C
严重眼损伤，类别1
联合国危险货物编号
UN3261
安全公开号
26-36/37/39-45
GHS危险声明
H314-H318
联合国危险货物等级
8
理化性质
熔点
97-101°C
描述信息
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分子图谱
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参考文献
• For the protection of alcohols, introduction of the group by the use of silver oxide has been recommended. Selective cleavage can be accomplished with DDQ (2,3-Dichloro-5,6-dicyanobenzoquinone, A11879) or by anodic oxidation. Many other benzyl-type protecting groups are unaffected by these conditions: Tetrahedron Lett., 31, 389 (1990). Indium metal in the presence of ammonium chloride is an effective deprotection system for 4-nitrobenzyl ethers and esters: J. Chem. Soc., Perkin 1, 955 (2001).
• Has been used as a protecting reagent for the carboxyl group in peptide synthesis: Helv. Chim. Acta, 42, 972 (1959); see 4-Nitrobenzyl chloride, A15749, and Appendix 6. Has also been used in ?-lactam synthesis. Cleavage by sodium sulfide avoids hydrogenolysis problems otherwise encountered with these sulfur-containing nuclei: J. Org. Chem., 43, 1243 (1978).