物质信息
ID:716894
名称和标识
IUPAC标准名
3-ethoxycyclohex-2-en-1-one
IUPAC传统名
3-ethoxycyclohex-2-en-1-one
别名
3-Ethoxy-2-cyclohexen-1-one3-乙氧基-2-环己烯-1-酮
化合物性质
理化性质
闪点
107°C(224°F)
沸点
76-78°C/1mm
密度
1.04
折射率
1.5060
安全信息
TSCA收录
否
产品相关信息
纯度
99%
描述信息
暂无数据
点击上传数据
分子图谱
暂无数据
点击上传数据
参考文献
• Useful intermediate for the preparation of 3-alkyl- or aryl-2-cyclohexen-1-ones, by addition of organometallic reagents and subsequent hydrolysis: J. Am. Chem. Soc., 70, 2174 (1948); 72, 1645 (1950); Helv. Chim. Acta, 36, 482 (1963). For an example of this transformation in the total synthesis of axane sesquiterpenoids, see: J. Org. Chem., 61, 473 (1996):
• Under conditions of kinetic enolate formation (LDA), alkylation occurs at the 6-position: the Stork-Danheiser kinetic alkylation procedure, which has found extensive use in alicyclic synthesis: J. Org. Chem., 38, 1775 (1973); Org. Synth. Coll., 7, 208 (1990) and references therein.