物质信息
ID:716776
名称和标识
IUPAC标准名
1,3-diethyl 2-acetamidopropanedioate
IUPAC传统名
1,3-diethyl 2-acetamidopropanedioate
别名
Acetamidomalonic acid diethyl esterDiethyl acetamidomalonate乙酰氨基丙二酸二乙酯
化合物性质
产品相关信息
纯度
98+%
安全信息
TSCA收录
是
RTECS编号
OO0360000
GHS危险声明
H303
GHS警示性声明
P312
理化性质
沸点
185°C/20mm
熔点
96-99°C
描述信息
暂无数据
点击上传数据
分子图谱
暂无数据
点击上传数据
参考文献
• For use in a novel pyrrole synthesis, see 1,4-Dichloro-2-butyne, A13300.
• Compare also Diethyl formamidomalonate, L01189.
• Substituents can also be introduced by Michael addition to a wide variety of acceptors: Synth. Commun., 18, 367 (1988).
• Intermediate for synthesis of racemic amino acids, by reaction with an electrophile, e.g alkyl halide, followed by hydrolysis and decarboxylation. The reactivity can be reversed by conversion to the dehydro-derivative, which then undergoes nucleophilic attack with alkyllithiums, Grignards, malonate anion, etc.: Angew. Chem. Int. Ed., 21, 203 (1982):
