物质信息
ID:715735
名称和标识
IUPAC传统名
diphenyl disulfide
IUPAC标准名
(phenyldisulfanyl)benzene
别名
Phenyl disulfideDiphenyl disulfide二苯基二硫醚
化合物性质
理化性质
沸点
310°C
熔点
58-62°C
安全信息
GHS危险声明
H315-H319-H335
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
RTECS编号
SS6825000
TSCA收录
是
安全公开号
26-37
欧盟危险性物质标志
刺激性 (Xi)GHS警示性声明
P280G-P305+P351+P338
危险公开号
36/37/38
产品相关信息
纯度
98%
描述信息
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分子图谱
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参考文献
• Also sulfenylates organolithium reagents from, e.g. lithiated furans: J. Org. Chem., 46, 2473 (1981).
• Alkyl halides under phase-transfer conditions give alkyl phenyl sulfides in good yields,: Synth. Commun., 12, 595 (1982), and alkenyl halides in the presence of CuI give alkenyl sulfides: Chem. Lett., 769 (1989).
• Sulfenylation agent for enolates of ketones, esters or carboxylic acid dianions: J. Am. Chem. Soc., 95, 6840 (1973); 98, 4887 (1976); Chem. Rev., 78, 363 (1978). Oxidation to the sulfoxide and thermal elimination can be used for the conversion of ketones to enones via thermal sulfoxide elimination, less frequently used than the selenoxide route (cf preceding entry), due to the higher temperatures required.
• For use as a catalyst in the photochemical cis-trans isomerization of olefins (used in the synthesis of the macrolide ricinelaidic acid lactone), see: Org. Synth. Coll., 7, 470 (1990).