物质信息
ID:715440
名称和标识
别名
2,5-FurandioneMaleic anhydride马来酸酐cis-Butenedioic Anhydride
IUPAC传统名
maleic anhydride
IUPAC标准名
2,5-dihydrofuran-2,5-dione
化合物性质
理化性质
熔点
52-56°C
闪点
103°C(217°F)
沸点
202°C
安全信息
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
腐蚀金属，类别1
腐蚀皮肤，类别1A，1B，1C
严重眼损伤，类别1
呼吸道过敏，类别1
生殖细胞突变，类别1A，1B，2
致癌性，类别1A，1B，2
生殖毒性，类别1A，1B，2
特定目标器官毒性 – 一次接触，类别1,2
特定目标器官毒性 – 反复接触，类别1,2
吸入危险，类别1
联合国危险货物编号
UN2215
欧盟危险性物质标志
有害性 (X)
腐蚀性 (C)GHS警示性声明
P260-P285-P303+P361+P353-P305+P351+P338-P405-P501A
RTECS编号
ON3675000
联合国危险货物等级
8
GHS危险声明
H334-H317-H314-H302
TSCA收录
是
保存注意事项
Moisture Sensitive
联合国危险货物包装类别(PG)
III
安全公开号
2-22-26-36/37/39-45
危险公开号
22-34-42/43
产品相关信息
纯度
98+%
描述信息
暂无数据
点击上传数据
分子图谱
暂无数据
点击上传数据
参考文献
• Also undergoes photochemical and thermal (2+2)-cycloadditions with alkenes. For reaction with 1-alkynes, see: Chem. Ber., 102, 3974 (1969).
• For use in combination with Urea hydrogen peroxide adduct, L13940, to generate peroxymaleic acid in epoxidation and Baeyer-Villiger reactions, see: Heterocycles, 36, 1075 (1993). Peroxymaleic acid can also be generated in situ from maleic anhydride and 30% H2O2 in NMP, and has been found to be a very effective oxidant for conversion of sulfides to sulfoxides. For a study of stoichiometric and catalytic oxidations with this system, see: J. Org. Chem., 61, 5693 (1996).
• For thermal (2+2)-cycloaddition with allene at high temperature, see: Org. Synth. Coll., 5, 459 (1973).
• Reactive dienophile. For a review of its Diels-Alder reactions, see: Org. React., 4, 1 (1948). For examples, see: Org. Synth. Coll., 3, 807 (1955); 4, 890 (1963). For reaction with Danishefsky's diene (1-Methoxy-3-trimethylsiloxy-1,3-butadiene, L14672), see: Org. Synth. Coll., 7, 312 (1990).