物质信息

ID:715272

2,6-二甲基苯酚

名称和标识
IUPAC传统名
2,6-dimethylphenol
IUPAC标准名
2,6-dimethylphenol
别名
2,6-Dimethylphenol2,6-二甲基苯酚2,6-Xylenol
数据登录号
Beilstein号
CAS号
默克索引号
化合物性质
安全信息
GHS危险声明
H301-H311-H314-H318-H411-H401
危险公开号
24/25-34-51/53
RTECS编号
ZE6125000
联合国危险货物包装类别(PG)
II
GHS警示性声明
P260-P301+P310-P303+P361+P353-P305+P351+P338-P361-P405-P501A
联合国危险货物等级
6.1
GHS危险品标识
GHS06
急性毒性(口服,皮肤接触,吸入),类别1,2,3
GHS05
腐蚀金属,类别1
腐蚀皮肤,类别1A,1B,1C
严重眼损伤,类别1
GHS09
对水环境的危害
急性危害,类别1
慢性危害,类别1,2
欧盟危险性物质标志
环境危害性 环境危害性 (N)
有毒 有毒 (T)
安全公开号
26-36/37/39-45-61
联合国危险货物编号
UN2261
TSCA收录
理化性质
沸点
203°C
熔点
44-48°C
闪点
78°C(172°F)
密度
1.15
产品相关信息
纯度
99%
描述信息
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分子图谱
暂无数据
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参考文献
• O-Alkylation of this hindered phenol by alkyl halides has been achieved using NaOH with micellar catalysis by (1-Hexadecyl)trimethylammonium bromide, A15235: Tetrahedron, 44, 6677 (1988). Alkylation of the Li salt with MeI occurs preferentially on carbon to give the dimer of 2,6,6-trimethyl-2,4-cyclohexadienone: Org. Synth. Coll., 5, 1092 (1973).
• Addition of lithiated 2,6-dimethylphenyl esters of alkanoic acids to carbonyl compounds has been used in a highly diastereoselective synthesis of ?-hydroxy acids. In some cases, only one of the two possible diastereomers is formed. For list of examples, see: Org. Synth. Coll., 7, 190 (1990).