物质信息
ID:715148
名称和标识
别名
Bismuth(III) nitrate pentahydrate五水合硝酸铋(III)
IUPAC传统名
bismuth(3+) ion pentahydrate trinitrate
IUPAC标准名
bismuth(3+) ion pentahydrate trinitrate
化合物性质
产品相关信息
纯度
98%
理化性质
密度
2.83
熔点
30°C dec.
安全信息
GHS警示性声明
P221-P210-P305+P351+P338-P302+P352-P405-P501A
欧盟危险性物质标志
刺激性 (Xi)
氧化性 (O)GHS危险品标识
氧化性气体，1类
氧化性液体，类别1,2,3
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
GHS危险声明
H272-H315-H319-H335
安全公开号
17-26-37-60
联合国危险货物等级
5.1
危险公开号
8-36/37/38
联合国危险货物编号
UN1477
联合国危险货物包装类别(PG)
II
TSCA收录
是
描述信息
暂无数据
点击上传数据
分子图谱
暂无数据
点击上传数据
参考文献
• Useful, easily handled oxidizing and nitrating agent in organic synthesis. Montmorillonite KSF acidic clay impregnated with bismuth nitrate was found to be an excellent reagent for high-yield aromatic nitration: Tetrahedron Lett., 41, 8017 (2000). Phenols can be nitrated with the salt itself in acetone, or without solvent: J. Org. Chem., 70, 9071 (2005). In the presence of montmorillonite, alcohols can be oxidized to carbonyl compounds: Synth. Commun., 31, 2691 (2001). Reagent for deprotection of oximes: Synthesis, 1010 (2001), and hydrazones: Synth. Commun., 32, 1917 (2001). Thioamides and thioureas are readily converted to their oxo-analogs: Tetrahedron Lett., 44, 591 (2003).
• Catalyst for a convenient, high-yield Michael addition of various substrates, including amines, imidazoles and indoles, to enones: J. Org. Chem., 68, 2109 (2003). Efficient catayst for tetrahydropyranylation and depyranylation of alcohols: Eur. J. Org. Chem., 4891 (2005).
• For a brief feature on uses of the reagent in organic synthesis, see: Synlett, 2699 (2005).