物质信息
ID:714986
名称和标识
IUPAC标准名
1,4,8,11-tetraazacyclotetradecane
IUPAC传统名
cyclam
别名
Cyclam1,4,8,11-Tetraazacyclotetradecane1,4,8,11-四氮环十四烷
化合物性质
产品相关信息
纯度
98+%
理化性质
熔点
184-188°C
安全信息
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
GHS警示性声明
P261-P305+P351+P338-P302+P352-P321-P405-P501A
安全公开号
26-37
危险公开号
36/37/38
保存注意事项
Air Sensitive
GHS危险声明
H315-H319-H335
RTECS编号
XA5254800
欧盟危险性物质标志
刺激性 (Xi)TSCA收录
否
描述信息
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分子图谱
暂无数据
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参考文献
• For use in synthesis of molecules with electroactive cavities, see (Ferrocenylmethyl)trimethylammonium iodide, 39399.
• The Ni(II) complex catalyzes the novel electrochemical reaction of epoxides with carbon dioxide to give good yields of cyclic carbonates: J. Chem. Soc., Chem. Commun., 43 (1995). A similar system catalyzes the electrochemical intramolecular reductive cyclization of a series of o-halogenated aryl alkenes: Tetrahedron Lett., 36, 4429 (1995):
• Complex with iron(II) triflate is an effective epoxidation catalyst: J. Am. Chem. Soc., 113, 7052 (1991).
• Nitrogen analogue of the crown ethers (see Appendix 2), forming stable complexes with metal ions: Inorg. Chem., 4,1102, 1109 (1965); Can. J. Chem., 48, 1481 (1970). For examples of use as a versatile ligand in coordination chemistry, see: Acc. Chem. Res., 11, 392 (1978); J. Chem. Soc., Chem. Commun., 1322 (1986); 1075 (1987); 156 (1988); Inorg. Chem., 26, 908 (1987); J. Am. Chem. Soc., 110, 3679 (1988).