物质信息
ID:366404
名称和标识
别名
Di-tert-butyl azodiformateNSC 109889DBADDi-tert-butyl azodicarboxylate偶氮二甲酸二叔丁酯Bis(1,1-dimethylethyl)azodicarboxylate
IUPAC标准名
N-{[(tert-butoxy)carbonyl]imino}(tert-butoxy)formamide
IUPAC传统名
N-[(tert-butoxycarbonyl)imino](tert-butoxy)formamide
化合物性质
安全信息
GHS警示词
Warning
GHS警示性声明
P261-P305+P351+P338
德国WGK号
3
保存温度
2-8°C
GHS危险声明
H315-H319-H335
危险公开号
36/37/38
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
个人保护装置
dust mask type N95 (US), Eyeshields, Gloves
欧盟危险性物质标志
刺激性 (Xi)MSDS下载
安全公开号
26-36
产品相关信息
纯度
≥98.0% (GC)
线性分子式
(CH3)3COCON=NCOOC(CH3)3
级别
purum
理化性质
熔点
89-92 °C
89-92 °C(lit.)
描述信息
Other Notes
酸不稳定试剂，用于温和分离产品的 Mitsunobu 反应8；烯醇化物和烷基锂的亲电氨基化和肼化反应9,10,11
Application
Reactant for:
• Preparation of hexapeptide key fragments via stereoselective selenocyclization/oxidative deselenylation or hydrazination/cyclization reactions1
• Asymmetric Michael addition reactions2
• Preparation of dipeptidyl peptidase IV dependent water-soluble prodrugs via Mitsunobu reaction3
• Synthesis of pyrroloisoquinoline template via stereoselective N-acyliminium-mediated cyclization and enolate amination for synthesis of peptidomimetic compounds4
• Barbier-type propargylation reactions5
• Synthesis of bacterial peptide deformylase (PDF) inhibitor fumimycin6
• Asymmetric amination of glycine Schiff bases7
酸不稳定试剂，用于温和分离产品的 Mitsunobu 反应8；烯醇化物和烷基锂的亲电氨基化和肼化反应9,10,11
Application
Reactant for:
• Preparation of hexapeptide key fragments via stereoselective selenocyclization/oxidative deselenylation or hydrazination/cyclization reactions1
• Asymmetric Michael addition reactions2
• Preparation of dipeptidyl peptidase IV dependent water-soluble prodrugs via Mitsunobu reaction3
• Synthesis of pyrroloisoquinoline template via stereoselective N-acyliminium-mediated cyclization and enolate amination for synthesis of peptidomimetic compounds4
• Barbier-type propargylation reactions5
• Synthesis of bacterial peptide deformylase (PDF) inhibitor fumimycin6
• Asymmetric amination of glycine Schiff bases7
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