物质信息
ID:358037
名称和标识
IUPAC标准名
hydroxy phenyl 4-methylbenzene-1-sulfonoperoxoyl iodide
IUPAC传统名
hydroxy phenyl 4-methylbenzenesulfonoperoxoyl iodide
别名
Hydroxy(phenyl)iodo tosylate[Hydroxy(4-toluenesulfonato)iodo]benzeneKoser’s reagentNSC 294176Iodosobenzene-I-mono-p-toluenesulfonatePhenyliodosyl hydroxide tosylateHTIBKoser 试剂羟基(甲苯磺酰氧代)碘苯Hydroxy(4-methylbenzenesulfonato-O)phenyliodine[Hydroxy(tosyloxy)iodo]benzene羟基甲苯磺酰碘苯
化合物性质
理化性质
熔点
131-137 °C
131-137 °C(lit.)
安全信息
GHS警示词
Warning
个人保护装置
dust mask type N95 (US), Eyeshields, Gloves
安全公开号
26-36
欧盟危险性物质标志
刺激性 (Xi)GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
德国WGK号
3
GHS危险声明
H315-H319
MSDS下载
GHS警示性声明
P305+P351+P338
危险公开号
36/38
产品相关信息
纯度
≥97.0% (AT)
级别
purum
线性分子式
CH3C6H4SO3I(OH)C6H5
描述信息
Other Notes
用于烯烃的选择性顺式-1,2-二对甲苯磺酰氧基化反应、对甲苯磺酰氧基化反应和其他转化的试剂9,10,11
Application
Reactant for:
• Ligand-free palladium-catalyzed Heck-type coupling reactions1
• Preparation of carbodiimides via dehydrosulfurization of thioureas2
• Preparation of nitriles by oxidative conversion of alcohols, aldehydes, and amines3
• Preparation of substituted anilines via aromatic aldoxime reaction4
• Preparation of tetrahydrofurans by oxidative cyclization of homoallylic alcohols5
• Preparation of isoxazoline N-Oxides from β-hydroxyketoximes via oxidative N-O coupling6
• Ring expansion in synthesis of aminopeptidase inhibitors7
• Oxidation and protonation reactions in acidic conditions8
用于烯烃的选择性顺式-1,2-二对甲苯磺酰氧基化反应、对甲苯磺酰氧基化反应和其他转化的试剂9,10,11
Application
Reactant for:
• Ligand-free palladium-catalyzed Heck-type coupling reactions1
• Preparation of carbodiimides via dehydrosulfurization of thioureas2
• Preparation of nitriles by oxidative conversion of alcohols, aldehydes, and amines3
• Preparation of substituted anilines via aromatic aldoxime reaction4
• Preparation of tetrahydrofurans by oxidative cyclization of homoallylic alcohols5
• Preparation of isoxazoline N-Oxides from β-hydroxyketoximes via oxidative N-O coupling6
• Ring expansion in synthesis of aminopeptidase inhibitors7
• Oxidation and protonation reactions in acidic conditions8
分子图谱
暂无数据
点击上传数据
参考文献
暂无数据
点击上传数据