物质信息
ID:345785
名称和标识
IUPAC标准名
trimethyl(trifluoromethyl)silane
IUPAC传统名
trifluoromethyltrimethylsilane
别名
TFMTMSTrifluoromethyltrimethylsilaneRuppert′s reagentTrimethyl(trifluoromethyl)silane solution三氟甲基三甲基硅烷 溶液Ruppert-Prakash reagent(Trifluoromethyl)trimethylsilane
化合物性质
产品相关信息
线性分子式
(CH3)3SiCF3
浓度
~2.0 M in THF
安全信息
欧盟危险性物质标志
刺激性 (Xi)
易燃性 (F)MSDS下载
危险公开号
11-19-36/37
联合国危险货物编号
1993
GHS警示词
Danger
联合国危险货物等级
3
GHS危险品标识
易燃气体类别1
易燃气溶胶，第1,2类
易燃液体，类别1,2,3
自反应物质和混合物，类型B，C，D，E，F
自燃液体类别1
自燃固体类别1
自我放热物质和混合物，类别1,2
与水接触的物质和混合物，放出易燃气体类别1,2,3
有机过氧化物，类别B，C，D，E，F
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
欧盟补充危害声明
May form explosive peroxides.
德国WGK号
3
GHS危险声明
H225-H319-H335
RID/ADR
UN 1993 3/PG 2
安全公开号
16-26
个人保护装置
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
联合国危险货物包装类别(PG)
2
GHS警示性声明
P210-P261-P305+P351+P338
理化性质
折射率
n20/D 1.386
密度
0.91 g/mL at 20 °C
闪点
1.4 °F
-17 °C
描述信息
包装
10, 50 mL in glass bottle
Application
Reactant for:
• Silver-mediated C-H trifluoromethylation of arenes1
• Preparation of trifluoromethyl ketone analog of L-arginine having contrasting inhibitory activity against human arginase I and histone deacetylase 82
• Organocatalyzed regio- and enantioselective allylic trifluoromethylation of Morita-Baylis-Hillman adducts3
• Palladium-catalyzed oxidative trifluoromethylation of indoles4
• Preparation of 5-HT1A antagonists5
• Used as difluorocarbene source6
10, 50 mL in glass bottle
Application
Reactant for:
• Silver-mediated C-H trifluoromethylation of arenes1
• Preparation of trifluoromethyl ketone analog of L-arginine having contrasting inhibitory activity against human arginase I and histone deacetylase 82
• Organocatalyzed regio- and enantioselective allylic trifluoromethylation of Morita-Baylis-Hillman adducts3
• Palladium-catalyzed oxidative trifluoromethylation of indoles4
• Preparation of 5-HT1A antagonists5
• Used as difluorocarbene source6
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