物质信息
ID:336283
名称和标识
别名
DIAD偶氮二甲酸二异丙酯Diisopropyl azodicarboxylateDiisopropyl azodiformate
IUPAC传统名
diisopropyl azodicarboxylate
IUPAC标准名
N-{[(propan-2-yloxy)carbonyl]imino}(propan-2-yloxy)formamide
化合物性质
安全信息
GHS危险品标识
对水环境的危害
急性危害，类别1
慢性危害，类别1,2
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
呼吸道过敏，类别1
生殖细胞突变，类别1A，1B，2
致癌性，类别1A，1B，2
生殖毒性，类别1A，1B，2
特定目标器官毒性 – 一次接触，类别1,2
特定目标器官毒性 – 反复接触，类别1,2
吸入危险，类别1
RID/ADR
UN 3082 9/PG 3
GHS警示词
Warning
危险公开号
36/37/38-40-48/20/22-51/53
德国WGK号
2
GHS警示性声明
P261-P273-P281-P305+P351+P338
联合国危险货物编号
3082
GHS危险声明
H315-H319-H335-H351-H373-H411
MSDS下载
安全公开号
26-36/37-61
保存温度
2-8°C
联合国危险货物包装类别(PG)
3
欧盟危险性物质标志
环境危害性 (N)
有害性 (Xn)个人保护装置
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
联合国危险货物等级
9
产品相关信息
纯度
98%
杂质
≤2% dichloromethane
线性分子式
(CH3)2CHOOCN=NCOOCH(CH3)2
理化性质
沸点
75 °C/0.25 mmHg(lit.)
闪点
222.8 °F
106 °C
折射率
n20/D 1.420(lit.)
密度
1.027 g/mL at 25 °C(lit.)
描述信息
General description
在铁催化剂催化下与二氧磷杂环己烷反应生成重排膦叶立德产物。8
包装
25, 100 g in poly bottle
5 g in glass bottle
Application
Reactant for preparation of:
• Chromenes resembling classical cannabinoids1
• MK-3281 inhibitor of the hepatitis C virus NS5B polymerase2
• Norbornene-based guanidine-rich polymers as mimcs of cell-penetrating peptides (CPP)3
• Analogues of the Pseudomonas aeruginosa quorum-sensing molecule N-(3-Oxododecanoyl)-l-homoserine lactone with immunosuppressive but non-LasR-inducing properties4
• Acceptor-donor-acceptor organic dyes for dye-sensitized solar cells5
• 1,3-dioxane-2-carboxylic acid derivatives as PPARα/γ dual agonists6
• Hydrazinophosphonates and hydrazinobisphosphonates via Mitsunobu and Arbuzov-type multicomponent application of the Morrison-Brunn-Huisgen betaine7
在铁催化剂催化下与二氧磷杂环己烷反应生成重排膦叶立德产物。8
包装
25, 100 g in poly bottle
5 g in glass bottle
Application
Reactant for preparation of:
• Chromenes resembling classical cannabinoids1
• MK-3281 inhibitor of the hepatitis C virus NS5B polymerase2
• Norbornene-based guanidine-rich polymers as mimcs of cell-penetrating peptides (CPP)3
• Analogues of the Pseudomonas aeruginosa quorum-sensing molecule N-(3-Oxododecanoyl)-l-homoserine lactone with immunosuppressive but non-LasR-inducing properties4
• Acceptor-donor-acceptor organic dyes for dye-sensitized solar cells5
• 1,3-dioxane-2-carboxylic acid derivatives as PPARα/γ dual agonists6
• Hydrazinophosphonates and hydrazinobisphosphonates via Mitsunobu and Arbuzov-type multicomponent application of the Morrison-Brunn-Huisgen betaine7
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