物质信息

ID:331423

5-(三氟甲基)二苯并噻吩鎓四氟硼酸盐

名称和标识
IUPAC传统名
8-(trifluoromethyl)-8-thiatricyclo[7.4.0.02,7]trideca-1(13),2,4,6,9,11-hexaen-8-ium tetrafluoroborate
别名
5-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate5-(三氟甲基)二苯并噻吩鎓四氟硼酸盐
IUPAC标准名
8-(trifluoromethyl)-8-thiatricyclo[7.4.0.02,7]trideca-1(13),2,4,6,9,11-hexaen-8-ium; tetrafluoroboranuide
数据登录号
PubChem SID
化合物性质
安全信息
个人保护装置
Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
MSDS下载
德国WGK号
3
产品相关信息
Empirical Formula (Hill Notation)
C13H8BF7S
纯度
97%
理化性质
熔点
162-164 °C(lit.)
描述信息
包装
1 g in glass bottle
Application

• Pd(II)-catalyzed trifluoromethylation1
• Copper-catalyzed trifluoromethylation of aryl boronic acids using a Collidine as a trifluoromethylating reagent2
• Pd-catalyzed electrophilic ortho-trifluoromethylation of arenes3 Used in the stereoselective preparation of
• Trifluoromethyl-substituted alkenes via copper-catalyzed trifluoromethylation of terminal alkenes4
• Trifluoromethyl-bearing quaternary carbon centers by Pd-catalyzed intramolecular decarboxylative allylation of α-trifluoromethyl β-keto esters5
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参考文献
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