物质信息
ID:308966
名称和标识
IUPAC标准名
N-[(ethoxycarbonyl)imino]ethoxyformamide
IUPAC传统名
diethyl azodicarboxylate
别名
NSC 679015Diethoxycarbonyldiazene solutionNSC 3474偶氮二甲酸二乙酯 溶液1,2-Ethoxycarbonyl diazene solutionUnifoam AZ-AE 200DEADDiethyl azodiformate solutionDiethyl azodicarboxylate solution
化合物性质
理化性质
密度
0.956 g/mL at 25 °C
沸点
116-117 °C
闪点
105.8 °F
41 °C
折射率
n20/D 1.4690
安全信息
保存温度
2-8°C
安全公开号
26-36/37-62
联合国危险货物包装类别(PG)
1
GHS警示性声明
P261-P281-P301+P310-P305+P351+P338-P331
GHS危险品标识
呼吸道过敏，类别1
生殖细胞突变，类别1A，1B，2
致癌性，类别1A，1B，2
生殖毒性，类别1A，1B，2
特定目标器官毒性 – 一次接触，类别1,2
特定目标器官毒性 – 反复接触，类别1,2
吸入危险，类别1
易燃气体类别1
易燃气溶胶，第1,2类
易燃液体，类别1,2,3
自反应物质和混合物，类型B，C，D，E，F
自燃液体类别1
自燃固体类别1
自我放热物质和混合物，类别1,2
与水接触的物质和混合物，放出易燃气体类别1,2,3
有机过氧化物，类别B，C，D，E，F
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
GHS警示词
Danger
欧盟危险性物质标志
有害性 (Xn)危险公开号
63-5-10-20-36/37/38-48/20-65
个人保护装置
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
联合国危险货物等级
3
联合国危险货物编号
3379
GHS危险声明
H226-H242-H304-H315-H319-H335+H336-H361d-H373
MSDS下载
RID/ADR
UN 3379 3/PG 1
德国WGK号
3
产品相关信息
线性分子式
C2H5OCON=NCOOC2H5
浓度
40 wt. % in toluene
描述信息
Application
常用于 Mitsunobo 反应的活化试剂。9
Reactant for preparation of:
• Immunostimulants α-Galactosylceramides1
• Cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases2
• Bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase3
• Derivatives of F200 and S383 with cannabinoid CB1 receptor binding activities4
• Aza-β-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes5Reagent for:
• Annulation of N-protected imines6
• α-thiocyanation of enolizable ketones with ammonium thiocyanate7
• Diels-Alder reactions8
General description
DOT Special Approval Submission is Under Review. Availability is Estimated as March 2012.
包装
25, 100 g in glass bottle
每 100g 约含 40g DEAD 溶质
每 25g 约含 10g DEAD 溶质
Warning
有毒性、刺激性、易燃
常用于 Mitsunobo 反应的活化试剂。9
Reactant for preparation of:
• Immunostimulants α-Galactosylceramides1
• Cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases2
• Bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase3
• Derivatives of F200 and S383 with cannabinoid CB1 receptor binding activities4
• Aza-β-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes5Reagent for:
• Annulation of N-protected imines6
• α-thiocyanation of enolizable ketones with ammonium thiocyanate7
• Diels-Alder reactions8
General description
DOT Special Approval Submission is Under Review. Availability is Estimated as March 2012.
包装
25, 100 g in glass bottle
每 100g 约含 40g DEAD 溶质
每 25g 约含 10g DEAD 溶质
Warning
有毒性、刺激性、易燃
分子图谱
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参考文献
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