物质信息
ID:307491
名称和标识
别名
Tricyclopentylphosphine三环戊基膦
IUPAC标准名
tricyclopentylphosphane
IUPAC传统名
tricyclopentylphosphane
化合物性质
安全信息
安全公开号
26-36/37/39-45
联合国危险货物等级
4.2
GHS警示性声明
P222-P231-P280-P305+P351+P338-P310-P422
GHS危险品标识
腐蚀金属，类别1
腐蚀皮肤，类别1A，1B，1C
严重眼损伤，类别1
易燃气体类别1
易燃气溶胶，第1,2类
易燃液体，类别1,2,3
自反应物质和混合物，类型B，C，D，E，F
自燃液体类别1
自燃固体类别1
自我放热物质和混合物，类别1,2
与水接触的物质和混合物，放出易燃气体类别1,2,3
有机过氧化物，类别B，C，D，E，F
德国WGK号
3
欧盟危险性物质标志
易燃性 (F)
腐蚀性 (C)联合国危险货物编号
2845
GHS警示词
Danger
个人保护装置
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
危险公开号
17-34
GHS危险声明
H250-H314
联合国危险货物包装类别(PG)
1
MSDS下载
RID/ADR
UN 2845 4.2/PG 1
理化性质
闪点
210 °C
410 °F
密度
0.986 g/mL at 20 °C(lit.)
0.979 g/mL at 25 °C
折射率
n20/D 1.538(lit.)
产品相关信息
Empirical Formula (Hill Notation)
C15H27P
纯度
97%
描述信息
包装
1, 5 g in glass bottle
Application
Cocatalyst for:
• Nickel-catalyzed cycloaddition of enones and alkynes1
• Rhodium-catalyzed allylation of aldehydes with homoallylic alcohols2
• Hydrocarbamoylation of alkynes by nickel/Lewis-acid catalysis3
• Alkenylation of imidazoles by nickel/Lewis acid catalysis
• Palladium-catalyzed Negishi cross-coupling reactions4
• PHosphine-catalyzed synthesis of 6-substituted 2-pyrones5
1, 5 g in glass bottle
Application
Cocatalyst for:
• Nickel-catalyzed cycloaddition of enones and alkynes1
• Rhodium-catalyzed allylation of aldehydes with homoallylic alcohols2
• Hydrocarbamoylation of alkynes by nickel/Lewis-acid catalysis3
• Alkenylation of imidazoles by nickel/Lewis acid catalysis
• Palladium-catalyzed Negishi cross-coupling reactions4
• PHosphine-catalyzed synthesis of 6-substituted 2-pyrones5
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