CAS 998-30-1|TRIETHOXYSILANE|triethoxysilane|triethoxysilane|Triethoxysilane|三乙氧基硅烷

基本信息

化学结构

分子式

C₆H₁₆O₃Si

分子量

164.27494

精确质量

164.0868709

电荷

InChI

InChI=1S/C6H16O3Si/c1-4-7-10(8-5-2)9-6-3/h10H,4-6H2,1-3H3

InChIKey

QQQSFSZALRVCSZ-UHFFFAOYSA-N

Canonic Smiles

CCO[SiH](OCC)OCC

Isomeric Smiles

CCO[SiH](OCC)OCC

计算属性

JChem

质子受体

质子供体

LogD (pH = 5.5)

0.7266

LogD (pH = 7.4)

0.7266

Log P

0.7266

摩尔折射率

36.1865

极化性

16.832813

极化表面积

27.69

可自由旋转的化学键

里宾斯基五规则

true

数据来源

名称和标识

别名

TRIETHOXYSILANETriethoxysilane三乙氧基硅烷

IUPAC标准名

triethoxysilane

IUPAC传统名

triethoxysilane

名称和标识

数据登录号

PubChem CID

维基百科标题

Chemspider ID

EC号

CAS号

PubChem SID

1620974852488934424864320

Beilstein号

1738989

MDL号

MFCD00009061

数据登录号

化合物性质

分子相关蛋白质

暂无数据

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分子图谱

暂无数据

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描述信息

MP Biomedicals

05221546

MP Biomedicals Rare Chemical collection

Wikipedia

Triethoxysilane

Sigma Aldrich

390143

包装
10, 50 mL in glass bottle
Application
在铂催化剂存在的情况下，与烯烃发生氢化硅烷化反应。可用作还原剂。1

描述信息

参考文献

PubChem文献

数据源提供

• In the presence of KF or CsF, reduces aldehydes and ketones to alcohols (via the silyl ether): Tetrahedron, 37, 2165 (1981). With CsF, enones can be reduced selectively to allylic alcohols in high yield: Tetrahedron., 39, 999 (1983).

• Versatile hydrosilylating agent. For use in combination with Ti(O-i-Pr) ₄ in a catalytic system for reduction of esters to alcohols, see: J. Org. Chem ., 57, 3751 (1992). CAUTION! Highly pyrophoric SiH ₄ can form in this reaction: J. Org. Chem., 57, 3221 (1993).

• The same system effects the otherwise difficult reduction of phosphine oxides to phosphines. The products may be reacted in situ with alkyl halides to give a convenient one-pot conversion of phosphine oxides to phosphonium salts: Tetrahedron Lett., 35, 625 (1994).

• Pd(0)-catalyzed silylation of aryl iodides provides a route to aryl triethoxysilanes: J. Org. Chem., 62, 8569 (1997).

参考文献

生物活性

PubChem BioAssay

生物活性