CAS 100-63-0|PHENYLHYDRAZINE|phenylhydrazine|phenylhydrazine|Hydrazinobenzene|苯肼|Phenylhydrazine|Monophenylhydrazine|Phenyldiazane|Hydrazinobenzene|PhNHNH2|Phenylhydrazin|hydrazobenzene|1-PHENYLHY...

PHENYLHYDRAZINEHydrazinobenzene苯肼PhenylhydrazineMonophenylhydrazinePhenyldiazaneHydrazinobenzenePhNHNH2Phenylhydrazinhydrazobenzene1-PHENYLHYDRAZINEmonophenylhydrazinePhenylhydrazinephenylhydrazine

IUPAC标准名

phenylhydrazine

IUPAC传统名

phenylhydrazine

名称和标识

数据登录号

EC号

CAS号

CHEMBL

KEGG ID

维基百科标题

Chemspider ID

CHEBI ID

27924CHEBI:27924CHEBI:25995CHEBI:8099CHEBI:44985

PubChem CID

7516

Beilstein号

606080

PubChem SID

24898342162091326248871532488715426697042

MDL号

MFCD00007573

默克索引号

147293

BRENDA数据库

5.1.1.131.7.2.64.1.1.361.11.1.132.6.1.704.3.1.156.1.1.161.4.9.22.6.1.62.3.1.54.1.1.933.5.5.14.3.1.192.6.1.622.6.1.41.1.3.155.4.3.34.1.2.262.6.1.554.4.1.133.5.1.62.3.1.293.5.99.52.1.2.14.8.1.21.5.3.151.1.1.1693.5.1.872.3.2.93.5.5.75.1.1.11.5.8.23.5.5.51.14.13.81.5.3.11.2.3.44.1.1.503.5.99.111.17.3.21.7.2.11.14.13.1052.3.2.23.5.1.41.1.1.282.1.1.32.6.1.133.5.1.912.5.1.494.5.1.21.2.3.11.5.99.124.6.1.22.6.1.212.6.1.1135.1.1.151.4.3.214.2.1.493.5.1.1011.11.1.194.4.1.13.5.4.41.1.1.291.1.3.42.6.1.371.4.3.22.6.1.74.4.1.152.6.1.21.1.3.94.1.1.924.1.1.571.11.1.73.1.1.834.3.1.22.6.1.54.2.1.844.3.1.181.1.1.261.1.3.394.1.2.493.5.2.141.4.3.192.6.1.192.5.1.483.5.3.95.4.3.64.3.1.31.5.99.62.6.1.451.2.2.B12.6.1.573.5.1.764.1.1.194.2.1.281.14.12.171.13.11.881.4.9.11.14.18.14.1.1.111.1.3.132.6.1.232.6.1.422.7.3.12.3.2.B31.4.3.41.21.4.12.3.1.474.1.1.641.17.1.51.4.3.131.4.3.224.1.3.12.5.1.47

EnzymePortal数据库

Q10725Q68AP4P0A790P84888P84887P0C7I4C3K630P83989Q76KX0Q7XSN8P50651

UniProt数据库

Q76KX0O82872P0C7I4Q7XSN8P50651P83989P86491Q68AP4P0A790Q75SP7P84888Q10725C3K630P84887

BindingDB数据库

SureChEMBL数据库

MetaCyc数据库

BKMS React数据库

Reaxys Registry

PubMed文献链接

71444472058585319627281

专利号

WO2006137083US2007197580EP1408035WO2006102758US2005159424EP1760078WO2007105203US2006058373US2008275092EP1889834US2007185115EP0937714WO2006092032EP1083171US2005000034

BRENDA Ligand数据库

CompTox数据库

MetaboLights数据库

SABIO-RK数据库

Gmelin ID

NMRShiftDB数据库

ACToR数据库

PDB数据库

PDBeChem数据库

数据登录号

化合物性质

分子相关蛋白质

PDB Bank

4N4M

2AGL

分子相关蛋白质

分子图谱

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描述信息

MP Biomedicals

02151837

Free Base Used as N-protecting reagent and for cleavage of phthaloyl group. 1 ml = approx. 1.10 g

05217394

MP Biomedicals Rare Chemical collection

Wikipedia

Phenylhydrazine

Sigma Aldrich

P26252

包装
5, 100, 500 g in glass bottle

78670

Application
用于铝、铬、钼、钛、锆的分光光度法测定

TRC

P335075

An aryl hydrazine used in the preparation of various dyes and pharmaceutical compounds. It is used in the investigation of oligosaccharides as well as the structure of photosystem II.

ChEBI

CHEBI:27924

A phenylhydrazine that is the monophenyl derivative of hydrazine.

描述信息

参考文献

PubChem文献

数据源提供

• Lattova, E. et al.: Meth. Mol. Biol., 534, 65 (2009)

• Anderson, L.B. et al.: J. Biol. Chem., 275, 4920 (2009)

• Derivatizing agent for the conversion of carbonyl compounds to their phenylhydrazones best known as intermediates in the Fischer indole synthesis, by cyclization under acidic conditions with loss of ammonia. The classical reagent is anhydrous ZnCl₂: Org. Synth. Coll., 3, 725 (1976). For reviews, see: Chem. Rev., 63, 373 (1963); 69, 227 (1969); Tetrahedron, 36, 161 (1980); Org. Prep. Proced. Int., 25,609 (1993). Milder cyclization conditions are sometimes effective, e.g.: dilute H₂SO₄: J. Org. Chem., 59, 3738 (1994); PCl₃: J. Chem. Soc., Chem. Commun., 563 (1981); Tetrahedron, 41, 4615 (1985). Cyclohexanone phenylhydrazone gives tetrahydrocarbazole on heating in acetic acid: Org. Synth. Coll., 4, 884 (1963).

• Methods used for the cleavage of phenylhydrazones include exchange by refluxing with acetone: J. Org. Chem., 40, 3302 (1975), or oxidative cleavage by Fe(NO₃)₃ on a clay support: Synthesis, 439 (1985).

参考文献

生物活性

PubChem BioAssay

生物活性

化合物信息

ID:103452