物质信息
ID:744769
名称和标识
IUPAC标准名
lithium(1+) ion perchlorate
IUPAC传统名
lithium(1+) ion perchlorate
别名
Lithium perchlorate, anhydrous高氯酸锂, 无水
化合物性质
理化性质
沸点
400°C dec.
外观
Granular, Ampouled under argon
熔点
236°C
密度
2.43
安全信息
保存注意事项
Hygroscopic
联合国危险货物编号
UN1481
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别1,2,3
氧化性气体，1类
氧化性液体，类别1,2,3
安全公开号
17-26-36
联合国危险货物等级
5.1
GHS危险声明
H270-H301-H315-H319-H335
GHS警示性声明
P220-P301+P310-P305+P351+P338-P302+P352-P405-P501A
欧盟危险性物质标志
有害性 (X)
氧化性 (O)危险公开号
8-22-36/37/38
TSCA收录
是
联合国危险货物包装类别(PG)
II
产品相关信息
纯度
99%
描述信息
暂无数据
点击上传数据
分子图谱
暂无数据
点击上传数据
参考文献
• The combination with an acyl anhydride is a powerful acylating agent for aromatic compounds under solvent-free conditions: Tetrahedron Lett., 43, 6331 (2002).
• Mild Lewis acid, often used as its diethyl ether complex; for a brief review of this reagent, see: Synlett, 649 (2002). The complex promotes formation of dithioacetals from aldehydes and dithiols: J. Org. Chem., 59, 4665 (1994), Michael additions of silyl enol ethers: J. Org. Chem., 60, 5024 (1995), and rearrangement of epoxides to carbonyl compounds, giving better selectivity than BF3: J. Org. Chem., 61, 1877 (1996). Efficient catalyst for transesterification of ?-keto esters under near-neutral conditions: Synlett, 1338 (2001). Has been found to increase dramatically the rate of the Baylis-Hillman reaction (see 1,4-Diazabicyclo[2.2.2]octane, A14003): Tetrahedron Lett., 40, 1539 (1999). Catalyzes the Michael addition of amines to ɑ,?-unsaturated esters, nitriles, amides or ketones under solvent-free conditions: Tetrahedron, 60, 383 (2004). Efficient catalyst for siliylation of hydroxyl groups under solvent-free, neutral conditions: Organometallics, 23, 1457 (2004).
• See also Lithium trifluoromethanesulfonate, 39322.