物质信息
ID:742323
名称和标识
IUPAC标准名
iodochlorane
IUPAC传统名
iodine monochloride
别名
ChloroiodideIodine monochloride单氯化碘
化合物性质
安全信息
TSCA收录
是
GHS危险品标识
腐蚀金属，类别1
腐蚀皮肤，类别1A，1B，1C
严重眼损伤，类别1
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
安全公开号
26-36/37/39-45
欧盟危险性物质标志
腐蚀性 (C)
有害性 (X)GHS危险声明
H314-H318-H302-H312
联合国危险货物等级
8
保存注意事项
Moisture & Light Sensitive
GHS警示性声明
P280-P303+P361+P353-P305+P351+P338-P310
联合国危险货物编号
UN1792
危险公开号
21/22-34
联合国危险货物包装类别(PG)
II
RTECS编号
NN1650000
理化性质
沸点
96-98°C
外观
Crystalline/Liquid
密度
3.1822
熔点
25-27°C
溶解度
Soluble in water, alcohol, ether, carbon disulfide
描述信息
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分子图谱
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参考文献
• More powerful electrophilic iodinating agent than iodine e.g. for aromatic substitution. For examples of its use in AcOH for aromatic iodination, see: Org. Synth. Coll., 2, 196, 343 (1943).
• Reacts with Benzyltrimethylammonium chloride, A16759 to form benzyltrimethylammonium dichloroiodide, a useful reagent for the iodination of phenols: Chem. Lett., 2109 (1987).
• For use in combination with NaN3 for the iodoazidation of an olefin, see: Org. Synth. Coll., 6, 893 (1988).
• The 1:1 complex with pyridine has been recommended as a mild and efficient iodinating agent for a wide range aromatic compounds: J. Chem. Res., 405 (1994). Condensed polycyclic iodides which cannot readily be prepared by direct iodination methods are formed by reaction of the same complex with the organomercurials: J. Chem. Res. (Synop.), 405 (1995).