物质信息

ID:737626

三氟甲烷磺酸锌

名称和标识
IUPAC标准名
zinc(2+) ion ditrifluoromethanesulfonate
别名
Zinc trifluoromethanesulfonate三氟甲烷磺酸锌Trifluoromethanesulfonic acid zinc saltZinc triflate
IUPAC传统名
zinc(2+) ion ditriflate
数据登录号
Beilstein号
化合物性质
安全信息
联合国危险货物编号
UN3261
联合国危险货物包装类别(PG)
III
GHS危险声明
H314-H318
安全公开号
26-36/37/39-45-60
保存注意事项
Hygroscopic
TSCA收录
欧盟危险性物质标志
腐蚀性 腐蚀性 (C)
GHS警示性声明
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
GHS危险品标识
GHS05
腐蚀金属,类别1
腐蚀皮肤,类别1A,1B,1C
严重眼损伤,类别1
联合国危险货物等级
8
危险公开号
34
产品相关信息
纯度
98%
理化性质
熔点
>300°C
描述信息
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分子图谱
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参考文献
• In combination with N-methylephedrine, catalyzes enantioselective addition of terminal alkynes to aldehydes to give propargylic alcohols in high yield and ee: J. Am. Chem. Soc., 122, 1806 (2000).
• Mild Lewis acid catalyst which promotes thioketalization, particularly of acid-sensitive substrates, with ethanedithiol: Tetrahedron Lett., 24, 169 (1983); J. Am. Chem. Soc., 105, 1662 (1983).
• Useful, alone or in combination with TMS chloride, for glycosidation reactions: Chem. Pharm. Bull., 40, 2909 (1992); 41, 201 (1993); 42, 1808 (1994).
• Promotes the aldol reaction of silyl enol ethers with aldehydes: Gazz. Chim. Ital., 123, 673 (1993).