物质信息
ID:737226
名称和标识
IUPAC标准名
N-(benzenesulfonyl)-S-phenylfluoranesulfonamido
IUPAC传统名
N-(benzenesulfonyl)-S-phenylfluoranesulfonamido
别名
N-氟苯磺酰亚胺N-FluorobenzenesulfonimideN-Fluorobis(phenylsulfonyl)amineAccuFluor NFSi
化合物性质
理化性质
熔点
114-118°C
安全信息
危险公开号
36/37/38
欧盟危险性物质标志
刺激性 (Xi)GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
TSCA收录
否
GHS警示性声明
P261-P305+P351+P338-P302+P352-P321-P405-P501A
GHS危险声明
H315-H319-H335
安全公开号
26-37
产品相关信息
纯度
97%
描述信息
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分子图谱
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参考文献
• For a review of electrophilic N-F fluorinating agents, see: Chem. Rev., 96, 1737 (1996).
• For directed fluorination of ortho-lithiated aromatics, see: Tetrahedron Lett., 35, 3465 (1994); ɑɑ-difluorination of benzylic phosphonate anions: Tetrahedron, 54, 1691 (1998); andof benzylic nitriles, tetrazoles and sulfonates: J. Org. Chem., 63, 8052 (1998).
• Stable, non-hygroscopic, glass-compatible mild electrophilic fluorinating agent, very soluble in acetonitrile, dichloromethane or THF, less soluble in toluene. Fluorinates aromatics, enolates, azaenolates and carbanions in high yield: Synlett, 187, 395 (1991); Tetrahedron Lett., 32, 1631 (1991); for diastereoselective fluorination of Li enolates of chiral carboximides, see: Tetrahedron Lett., 33, 1153 (1992). Asymmteric fluorinations have been effected in the presence of a Pd-BINAP catalyst system at room temperature in an ionic liquid: Org. Lett., 5, 3225 (2003).