物质信息
ID:722713
名称和标识
IUPAC传统名
tetrapropylammonium rutheniumoylolate
IUPAC标准名
tetrapropylazanium rutheniumoylolate
别名
TPAP四正丙基过钌(VII)酸铵Tetra-n-propylammonium perruthenate(VII)
化合物性质
安全信息
保存注意事项
Hygroscopic
GHS警示性声明
P221-P210-P305+P351+P338-P302+P352-P405-P501A
危险公开号
5-8-36/37/38
联合国危险货物包装类别(PG)
III
TSCA收录
否
欧盟危险性物质标志
刺激性 (Xi)
氧化性 (O)安全公开号
17-26-37
联合国危险货物等级
5.1
GHS危险声明
H272-H315-H319-H335
GHS危险品标识
氧化性气体，1类
氧化性液体，类别1,2,3
急性毒性（口服，皮肤接触，吸入），类别4
皮肤刺激，类别2
眼刺激，类别2
皮肤过敏，类别1
特定目标器官毒性 -一次接触，类别3
联合国危险货物编号
UN1479
产品相关信息
纯度
98%
理化性质
熔点
160°C dec.
描述信息
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分子图谱
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参考文献
• For a brief feature on uses in synthesis, see: Synlett, 824 (2007).
• Selective, catalytic oxidant introduced by Ley. Normally used in combination with N-methylmorpholine-N-oxide as the stoichiometric reoxidant and 4A molecular sieves to remove water. Preferred solvents are dichloromethane and acetonitrile. Primary and secondary alcohols are oxidized to aldehydes and ketones in high yield: J. Chem. Soc., Chem. Commun., 1625 (1987). For an example of alcohol to aldehyde oxidation in the partial synthesis of the acyl tetronic acid ionophore tetronasin, see: Tetrahedron Lett., 35, 319 (1994). Also useful for a number of other oxidations such as lactols to lactones and sulfides to sulfones. For oxidation of secondary amines to imines, and of hydroxylamines to nitrones, see: Tetrahedron Lett., 35, 6567, 6571 (1994).
• For a comprehensive review of this reagent, see: Synthesis, 639 (1994). For a review of ruthenium oxo-complexes as organic oxidants, see: Chem. Soc. Rev., 21, 179 (1992).