物质信息

ID:721889

名称和标识
IUPAC传统名
1,2-benzenedimethanol
别名
o-Xylene-alpha,alpha'-diol1,2-Benzenedimethanol1,2-Bis(hydroxymethyl)benzene邻苯二甲醇
IUPAC标准名
[2-(hydroxymethyl)phenyl]methanol
数据登录号
CAS号
Beilstein号
化合物性质
安全信息
TSCA收录
理化性质
熔点
59-64°C
产品相关信息
纯度
97%
描述信息
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分子图谱
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参考文献
• Has also been employed for the protection of boronic acids, by reaction in THF in the presence of a dehydrating agent, e.g. Na2SO4. These derivatives can be readily cleaved by hydrogenolysis or hydrolysis: Tetrahedron Lett., 37, 6705 (1996).
• The 7-membered cyclic orthoformates, formed with triethyl or trimethyl orthoformate, are superior reagents for the protection of carbonyl groups as their 2,4-benzodioxepine derivatives. These can be readily cleaved in high yield by Pd-catalyzed hydrogenolysis: Tetrahedron Lett., 30, 4165 (1989); J. Am. Chem. Soc., 116, 558 (1994).