物质信息
ID:719586
名称和标识
IUPAC传统名
O-methylhydroxylamine hydrochloride
IUPAC标准名
O-methylhydroxylamine hydrochloride
别名
Methoxylamine hydrochlorideO-METHYLHYDROXYLAMINE HYDROCHLORIDE甲氧胺盐酸盐Methoxylamine hydrochloride
化合物性质
安全信息
RTECS编号
NC3980000
GHS危险品标识
急性毒性（口服，皮肤接触，吸入），类别1,2,3
对水环境的危害
急性危害，类别1
慢性危害，类别1,2
腐蚀金属，类别1
腐蚀皮肤，类别1A，1B，1C
严重眼损伤，类别1
欧盟危险性物质标志
有害性 (X)
环境危害性 (N)
腐蚀性 (C)TSCA收录
是
联合国危险货物等级
8
危险公开号
22-34-43-50
安全公开号
26-36/37/39-45-61
联合国危险货物编号
UN3261
联合国危险货物包装类别(PG)
III
GHS警示性声明
P260-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501A
保存注意事项
Hygroscopic
GHS危险声明
H301-H317-H314-H318-H400
理化性质
熔点
ca 148°C dec.
产品相关信息
纯度
98+%
描述信息
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分子图谱
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参考文献
• In the presence of KO-t-Bu and a copper catalyst in DMF, aminates nitroarenes at the ortho (predominantly) and para positions: J. Org. Chem., 61, 442 (1996).
• Reacts with aldehydes and ketones to give O-methyloximes: J. Org. Chem., 27, 914 (1962); 28, 1523 (1963); Anal. Biochem., 22, 284 (1968). Open-chain aldoses have been prepared by ozonolysis of the methoximes of fully-acylated sugars: J. Org. Chem., 54, 4957 (1989).
• As with oximes, the lithiation of methoximes results in abstraction of a proton syn to the oxygen function (coordination stabilization): J. Org. Chem., 41, 439 (1976). For a review of the alkylation of carbonyl compounds via their nitrogen-containing derivatives, see: Synthesis, 517 (1983).